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- W1994254710 abstract "The relativistic linked-cluster many-body perturbation theory has been applied to calculate the hyperfine fields in the ${mathrm{Zn}}^{+}$, ${mathrm{Cd}}^{+}$, and ${mathrm{Hg}}^{+}$ ions. We calculate field strengths of 451ifmmodepmelsetextpmfi{}9, 795ifmmodepmelsetextpmfi{}15, and 2642ifmmodepmelsetextpmfi{}63 T, respectively, values in good agreement with experiment for ${mathrm{Cd}}^{+}$, and in excellent agreement for ${mathrm{Hg}}^{+}$. No experimental data are available for the ${mathrm{Zn}}^{+}$ system. We will discuss the contributions to these total fields coming from the valence, one-electron perturbation, and many-body correlation mechanisms, and compare these contributions with those calculated in the alkali-metal atom and alkaline-earth ion systems that also have a single electron outside closed shells. We will also discuss the importance of third- and higher-order correlation contributions, which are rather large in these systems." @default.
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- W1994254710 date "1991-07-01" @default.
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- W1994254710 title "Theory of hyperfine interactions in positive ions isoelectronic with the noble-metal atoms" @default.
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- W1994254710 doi "https://doi.org/10.1103/physreva.44.121" @default.
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