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- W1994261663 abstract "In an effort to understand the first stages of the reduction of nitroarenes to anilines by palladium/phenanthroline complexes and suspecting that arylhydroxylaminato complexes may be intermediates in this process, we investigated the reactivity of [Pd(Neoc)(NO3)2] (Neoc = neocuproine = 2,9-dimethyl-1,10-phenanthroline) with 3,5-dichlorophenylhydroxylamine. Spectroscopic evidence indicates that the desired [Pd(Neoc)(ONHC6H3Cl2)(NO3)] is indeed formed, but the complex is not stable and decomposes within a few hours. Two of the decomposition products were characterized by single crystal X-ray diffraction. They are a N-aryl-N-nitrosohydroxylaminato complex, [Pd(Neoc)(ON(3,5-C6H3Cl2)NO)][NO3] (major decomposition product) and a nitro-nitrate complex [Pd(Neoc)(NO2)(NO3)]. The results indicate that the nitrate ion is not innocent in the starting complex and oxidize hydroxylamine, being reduced itself to NO2− and NO." @default.
- W1994261663 created "2016-06-24" @default.
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- W1994261663 date "1974-01-01" @default.
- W1994261663 modified "2023-10-18" @default.
- W1994261663 title "Preparation and structure of tris- [(tri-t-butylphosphine)(nitrosobenzene)palladium]" @default.
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- W1994261663 doi "https://doi.org/10.1016/s0020-1693(00)93674-0" @default.
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