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• W1994278613 endingPage "1515" @default.
• W1994278613 startingPage "1509" @default.
• W1994278613 abstract "Perchlorate (ClO 4 − ) has recently emerged as a widespread contaminant in drinking water and groundwater supplies in the United States, and a need exists for rapid detection and monitoring of this contaminant. In this study, surface-enhanced Raman spectroscopy (SERS) was studied as a means of ClO 4 − detection, and new sol-gel-based SERS substrates were developed by self-assembly of silver colloidal nanoparticles with various functionalized silane reagents. These substrate materials were tailored to allow detection of ClO 4 − in water with improved sorptivity, stability, and sensitivity and with the ability to detect ClO 4 − at concentrations as low as 10 −6 M (or 100 μg/L) with good reproducibility. Similar techniques were used to fabricate capillary SERS flow cells by assembling functionalized silver nanoparticles capable of attracting ClO 4 − to the SERS surface or the internal wall of glass capillaries. These capillary flow cells could be readily configured to allow for in situ, nondestructive detection of ClO 4 − via fiber optics." @default.
• W1994278613 created "2016-06-24" @default.
• W1994278613 creator A5046597133 @default.
• W1994278613 creator A5089109883 @default.
• W1994278613 date "2005-12-01" @default.
• W1994278613 modified "2023-09-25" @default.
• W1994278613 title "New Surface-Enhanced Raman Spectroscopy Substrates via Self-Assembly of Silver Nanoparticles for Perchlorate Detection in Water" @default.
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• W1994278613 doi "https://doi.org/10.1366/000370205775142458" @default.
• W1994278613 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/16390591" @default.
• W1994278613 hasPublicationYear "2005" @default.
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