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- W1994281085 abstract "The use of the parameter carbon number equivalent, Nc*, as analyte descriptor for neutral hydrophobic solutes in EKC is investigated. The carbon number equivalent of an analyte is defined analogously to the retention index, RI, however, it is directly calculated from the regression line plotting for the members of a homologous series the logarithm of the retention factor against the number of methylene units Nc in the alkyl chain. This plot can be obtained by using simultaneously an iteration procedure for the calculation of tMC. For separation electrolytes containing SDS as micellar phase employing ACN, urea, and CaCl2 as additives within a wide span of concentrations the parameter Nc* is quasi-independent of the composition of the separation electrolyte, being of importance concerning identification of analytes and improving repeatability and reproducibility. With known octanol–water partition coefficients for the members of the homologous series taken as reference it is possible to transform the conventional time scale of an electropherogram into a scale of Nc* or a scale of log POW. Due to the quasi-independence of Nc* from the composition of the separation electrolyte these transformed electropherograms can be used as normalized electropherograms for identification purposes. It is also shown that the linear dependence of log POW on Nc can be the basis of the determination of octanol–water partition coefficients of solutes within a very large range (−4 ≤ log POW ≤ 9)." @default.
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- W1994281085 date "2008-02-01" @default.
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- W1994281085 title "Separation of very hydrophobic analytes by MEKC. II. Carbon number equivalents as analyte descriptors – influence of the composition of the separation electrolyte" @default.
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- W1994281085 doi "https://doi.org/10.1002/elps.200700365" @default.
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