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- W1994295045 abstract "To decide whether the cyclotrimerization of diarylacetylene with diarylacetylene hexacarbonyl dicobalt as catalyst, proceeds via a cyclobutadiene intermediate, two experiments were performed, both relying on the experimentally verified hypothesis that a 3-methoxyphenyl ring can be considered as an ideally chemically labelled phenyl ring : (1) the co-cyclotrimerization of diphenylacetylene with bis(3-methoxyphenyl)acetylene, and (2) the cyclotrimerization of 1-(3-methoxyphenyl)-2-phenylacetylene. Analysis of the resulting meta methoxy substituted hexaphenylbenzenes using our chemical shift model, is for both experiments conclusive against the involvement of a cyclobutadiene intermediate." @default.
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- W1994295045 date "2010-09-01" @default.
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- W1994295045 title "Conclusive evidence against a cyclobutadiene intermediate in the cyclotrimerization of diarylacetylene using the diarylacetylene hexacarbonyl dicobalt complex as catalyst" @default.
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- W1994295045 doi "https://doi.org/10.1002/bscb.19880970204" @default.
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