FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W1994301342> ?p ?o ?g. }

• W1994301342 endingPage "8015" @default.
• W1994301342 startingPage "8009" @default.
• W1994301342 abstract "Propionyl chloride and perfluoropropionyl chloride have been characterized using chirped pulse Fourier transform microwave spectroscopy between the frequency range of 8 and 14 GHz. Molecules were studied in separate experiments in supersonic expansions of argon. The (35)Cl, (37)Cl, and each of the monoisotopic (13)C substituted isotopologues of propionyl chloride were observed. The (35)Cl and (37)Cl isotopologues of perfluoropropionyl chloride were observed. Analyses of the resulting microwave spectra have yielded spectroscopic constants for the target molecules. The analyses indicate that, under the conditions of these experiments, both molecules are only detectable as cis conformers in which angleCCCO = 0 degrees . Comparisons are made between the electronic and geometric structure of propionyl chloride and perfluoropropionyl chloride, and also other acyl chlorides. The data produced are relevant in regards to quantifying the known destabilizing effect of perfluoroalky chains on carbonyl groups. Distinct differences in electronegativity between the CH(3)CH(2)CO- and CF(3)CF(2)CO- groups are discussed. Methyl group internal rotation is observed for propionyl chloride and has been analyzed to produce a V(3) barrier height." @default.
• W1994301342 created "2016-06-24" @default.
• W1994301342 creator A5004472184 @default.
• W1994301342 creator A5037105394 @default.
• W1994301342 creator A5038824633 @default.
• W1994301342 creator A5090756708 @default.
• W1994301342 date "2010-07-12" @default.
• W1994301342 modified "2023-10-14" @default.
• W1994301342 title "Some Geometric and Electronic Structural Effects of Perfluorinating Propionyl Chloride" @default.
• W1994301342 cites W1968510627 @default.
• W1994301342 cites W1970493748 @default.
• W1994301342 cites W1971275758 @default.
• W1994301342 cites W1979091167 @default.
• W1994301342 cites W1983586529 @default.
• W1994301342 cites W1992312551 @default.
• W1994301342 cites W1992680189 @default.
• W1994301342 cites W1994668496 @default.
• W1994301342 cites W1996846370 @default.
• W1994301342 cites W2001922453 @default.
• W1994301342 cites W2003214626 @default.
• W1994301342 cites W2003241740 @default.
• W1994301342 cites W2012683273 @default.
• W1994301342 cites W2022950330 @default.
• W1994301342 cites W2023271753 @default.
• W1994301342 cites W2023822037 @default.
• W1994301342 cites W2024474944 @default.
• W1994301342 cites W2038533471 @default.
• W1994301342 cites W2039554515 @default.
• W1994301342 cites W2041706866 @default.
• W1994301342 cites W2046025157 @default.
• W1994301342 cites W2051187895 @default.
• W1994301342 cites W2054899118 @default.
• W1994301342 cites W2069723789 @default.
• W1994301342 cites W2081524721 @default.
• W1994301342 cites W2081734031 @default.
• W1994301342 cites W2083002840 @default.
• W1994301342 cites W2085336624 @default.
• W1994301342 cites W2089773530 @default.
• W1994301342 cites W2143981217 @default.
• W1994301342 cites W2146989449 @default.
• W1994301342 cites W2148284063 @default.
• W1994301342 cites W2150697053 @default.
• W1994301342 cites W2151220474 @default.
• W1994301342 cites W2166796013 @default.
• W1994301342 cites W2066067275 @default.
• W1994301342 doi "https://doi.org/10.1021/jp103966e" @default.
• W1994301342 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/20666547" @default.
• W1994301342 hasPublicationYear "2010" @default.
• W1994301342 type Work @default.
• W1994301342 sameAs 1994301342 @default.
• W1994301342 citedByCount "27" @default.
• W1994301342 countsByYear W19943013422012 @default.
• W1994301342 countsByYear W19943013422013 @default.
• W1994301342 countsByYear W19943013422014 @default.
• W1994301342 countsByYear W19943013422015 @default.
• W1994301342 countsByYear W19943013422016 @default.
• W1994301342 countsByYear W19943013422017 @default.
• W1994301342 countsByYear W19943013422018 @default.
• W1994301342 countsByYear W19943013422019 @default.
• W1994301342 countsByYear W19943013422020 @default.
• W1994301342 crossrefType "journal-article" @default.
• W1994301342 hasAuthorship W1994301342A5004472184 @default.
• W1994301342 hasAuthorship W1994301342A5037105394 @default.
• W1994301342 hasAuthorship W1994301342A5038824633 @default.
• W1994301342 hasAuthorship W1994301342A5090756708 @default.
• W1994301342 hasConcept C113196181 @default.
• W1994301342 hasConcept C13934619 @default.
• W1994301342 hasConcept C147597530 @default.
• W1994301342 hasConcept C147789679 @default.
• W1994301342 hasConcept C161790260 @default.
• W1994301342 hasConcept C177293861 @default.
• W1994301342 hasConcept C178790620 @default.
• W1994301342 hasConcept C185592680 @default.
• W1994301342 hasConcept C18705241 @default.
• W1994301342 hasConcept C2778695967 @default.
• W1994301342 hasConcept C2779000391 @default.
• W1994301342 hasConcept C2779028575 @default.
• W1994301342 hasConcept C31100168 @default.
• W1994301342 hasConcept C32909587 @default.
• W1994301342 hasConcept C75473681 @default.
• W1994301342 hasConceptScore W1994301342C113196181 @default.
• W1994301342 hasConceptScore W1994301342C13934619 @default.
• W1994301342 hasConceptScore W1994301342C147597530 @default.
• W1994301342 hasConceptScore W1994301342C147789679 @default.
• W1994301342 hasConceptScore W1994301342C161790260 @default.
• W1994301342 hasConceptScore W1994301342C177293861 @default.
• W1994301342 hasConceptScore W1994301342C178790620 @default.
• W1994301342 hasConceptScore W1994301342C185592680 @default.
• W1994301342 hasConceptScore W1994301342C18705241 @default.
• W1994301342 hasConceptScore W1994301342C2778695967 @default.
• W1994301342 hasConceptScore W1994301342C2779000391 @default.
• W1994301342 hasConceptScore W1994301342C2779028575 @default.
• W1994301342 hasConceptScore W1994301342C31100168 @default.
• W1994301342 hasConceptScore W1994301342C32909587 @default.
• W1994301342 hasConceptScore W1994301342C75473681 @default.
• W1994301342 hasIssue "30" @default.
• W1994301342 hasLocation W19943013421 @default.
• W1994301342 hasLocation W19943013422 @default.

• next