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- W1994317247 abstract "The interaction between ionic surfactants and phosphatidylcholine vesicles, which are prepared without addition of buffer and salt, is investigated by conductivity measurements. On the basis of the vesicle acting as a trap of charge carriers, the bilayer/aqueous phase partition coefficient K and the surfactant/lipid molar ratio Re of nine surfactants are determined. The thermodynamic consistency is satisfied by the measured parameters. The effects of the alkyl chain length (C10–C16) and ionic head group are then studied. The inverse partition coefficient K−1 is linearly related to the critical micelle concentration. The solubilizing ability Reb is a consequence of the competition between the surfactant incorporation into the bilayer and the formation of micelles. Consequently, the K parameter rises whereas the Reb parameter declines as the chain length is increased. The influence due to addition of salt is also discussed." @default.
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- W1994317247 date "2001-11-01" @default.
- W1994317247 modified "2023-09-27" @default.
- W1994317247 title "The interactions between ionic surfactants and phosphatidylcholine vesicles: Conductometry" @default.
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- W1994317247 doi "https://doi.org/10.1063/1.1407004" @default.
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