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- W1994323558 abstract "The synthesis of the title compound 5 was accomplished by a high-yield thermal rearrangement of the ozonide (3) of dimethyl 5,6-O-isopropylidene-7-oxabicyclo[2.2.1]hept-2-ene-exo-5,6-diol-2,3-dicarboxylate (2a), which is obtained in 30% yield from the Diels–Alder adduct of furan and dimethyl acetylenedicarboxylate. Catalytic reduction of 5 gave methyl 2,3-O-iso-propylidene-β-DL-talofuranuronate (8) as the major product, accompanied by a small amount of the allo isomer 9." @default.
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- W1994323558 date "1975-09-15" @default.
- W1994323558 modified "2023-10-17" @default.
- W1994323558 title "A Total Synthesis of Dimethyl 2,3-<i>O</i>-Isopropylidene-l-<i>O</i>-oxalyl-β-<scp>DL</scp>-<i>ribo</i>-hexofuran-5-ulosuronate" @default.
- W1994323558 doi "https://doi.org/10.1139/v75-383" @default.
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