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• W1994333929 abstract "A series of S-hydrogen phosphorothioates have been converted to the corresponding S-trifluoromethyl derivatives upon reaction with the electrophilic trifluoromethylation reagent 1 (trifluoromethyl 1,3-dihydro-3,3-dimethyl-1,2-benziodoxole). Relative rate data were obtained by 19F NMR monitoring of competition experiments and were evaluated by means of the Taft equation. A high positive polar sensitivity factor of 2.55 was found for electron-rich substrates and a negative one of −0.37 for electron-poor ones, implying the involvement of two different rate-determining steps. Furthermore, the reaction was found to be unaffected by steric factors." @default.
• W1994333929 created "2016-06-24" @default.
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• W1994333929 date "2011-04-18" @default.
• W1994333929 modified "2023-10-18" @default.
• W1994333929 title "Electrophilic Trifluoromethylation of <i>S</i>-Hydrogen Phosphorothioates" @default.
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• W1994333929 doi "https://doi.org/10.1021/jo200522w" @default.
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