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- W1994334628 abstract "Abstract A new ESR hyperfine structure (hfs) of Cu 2+ was detected in moderately (cooling rate ≈ 3 K/s) and rapidly (10 3 –10 5 K/s) quenched borate glasses with Na 2 O content smaller than 5 mol% in addition to the already reported three patterns, spectra I, II and III, for the moderately quenched borate glasses with 5 ⪅ [Na 2 O]⪅13, 20 ⪅ [Na 2 O] ⪅37 and 55 ⪅ [Na 2 O] ⪅ 75, respectively. The ESR parameters of this spectrum were much the same as those of II, but a significant difference was observed between thermal stabilities of these spectra. The newly observed spectrum was named spectrum II′. A superposition of spectra II′ and I was seen in low alkali borate glasses ([Na 2 O] ⪅ 5 mol%). The relative intensity of II′ to I increased remarkably with increasing quenching rate of the melts and with decreasing alkali content under the same quenching condition. In addition, spectrum II′ was found to relax into I upon thermal annealing of the glasses. Similar changes were observed also in ESR of the γ-induced Cd + with 5s 1 electronic configuration. A tentative model to account for the spectral changes was proposed on the basis of the characteristics of B—O bonding." @default.
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- W1994334628 date "1983-04-01" @default.
- W1994334628 modified "2023-09-27" @default.
- W1994334628 title "Effect of quenching rate and annealing on ESR of Cu2+ and γ-induced Cd+ in low alkali borate glasses" @default.
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- W1994334628 doi "https://doi.org/10.1016/0022-3093(83)90003-0" @default.
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