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- W1994340692 abstract "I n the present work, the gaseous and liquid decomposition products of 50 mass% hydroxylamine/water solution were measured for samples subsequent to a thermally induced runaway reaction. The noncondensablegas phase composition was approximately 70 mol% N2, 24 mol% N2O, 4mol% NO, and 2 mol% H2, and ammonia was detected in the liquid residue. Based on analysis of the gas phase decomposition products, the following overall decomposition reaction (summation of several series and parallel reaction mechanisms taking place during the experiment) was determined: 157NH2OHliq → 61NH3gas + 35N2gas + 12N2Ogas + 2NOgas + 143H2Ogas + H2gas This reaction has an associated theoretical standard heat of reaction of −124 kJ mol−1(−29.6 kcal mol−1), which is consistent with −117 kJ mol−1 (−28 kcal mol−1) estimated for the hydroxylamine overall heat of decomposition reported previously." @default.
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- W1994340692 date "2003-03-01" @default.
- W1994340692 modified "2023-10-16" @default.
- W1994340692 title "Decomposition Products of 50 Mass% Hydroxylamine/Water Under Runaway Reaction Conditions" @default.
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- W1994340692 doi "https://doi.org/10.1205/095758203321832598" @default.
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