FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W1994347680> ?p ?o ?g. }

• W1994347680 endingPage "2871" @default.
• W1994347680 startingPage "2863" @default.
• W1994347680 abstract "The reactivity of [Os3H(CO)10(MeCN){Si(OR)3}](R = Me or Et) towards diphosphines has been studied. The compounds [Os3H(CO)10{Si(OR)3}(dppm)] are formed in high yield from the reaction with bis(diphenylphosphino)methane (dppm). Formation of three different products [Os3H(CO)10{Si(OR)3}(dppe-P)], [{Os3H(CO)10[Si(OR)3]}2(µ-dppe)], and [Os3(CO)10(dppe-PP′)], has been observed from the reaction with 1,2-bis(diphenylphosphino)ethane (dppe). The product distribution is strictly dependent on the reaction stoicheiometry. The structure of [Os3H(CO)10-{Si(OEt)3}(dppe-P)] has been determined by X-ray diffraction [monoclinic, space group P21/c, a= 18.092(4), b= 11.924(1), c= 23.210(5)Å, β= 108.29(2)°, Z= 4] unambiguously establishing monodentate co-ordination of the dppe ligand. The dimeric nature of [{Os3H(CO)10[Si(OMe)3]}2(µ-dppe)] has been crystallographically determined [monoclinic, space group C2/c, a= 18.07(2), b= 14.134(3), c= 26.60(1)Å, β= 111.72(5)°, Z= 8]. An X-ray crystallographic characterization of [Os3(CO)10(dppe-PP′)] shows the chelating mode of the dppe ligand [monoclinic, space group P21/c, a= 15.527(2), b= 10.405(5), c= 22.519(3)Å, β= 94.01 (1)°, Z= 4]. The compounds [{Os3H(CO)10[Si(OR)3]}2(µ-dppe)] can be prepared alternatively from [{Os3(CO)10(MeCN)}2(µ-dppe)] and the appropriate silane SiH(OR)3(R = Me or Et)." @default.
• W1994347680 created "2016-06-24" @default.
• W1994347680 creator A5031287240 @default.
• W1994347680 creator A5036230982 @default.
• W1994347680 creator A5040355874 @default.
• W1994347680 creator A5054593712 @default.
• W1994347680 creator A5083086799 @default.
• W1994347680 creator A5091030530 @default.
• W1994347680 date "1990-01-01" @default.
• W1994347680 modified "2023-10-10" @default.
• W1994347680 title "Reactivity of [Os₃H(CO)₁₀(MeCN){Si(OR)₃}](R = Me or Et) towards diphosphines. X-Ray crystal structures of [Os₃H(CO)₁₀{Si(OEt)₃}(dppe)], [{Os₃H(CO)₁₀[Si(OMe)₃]}₂(µ-dppe)] and [Os₃(CO)₁₀(dppe)](dppe = Ph₂PCH₂CH₂PPh₂)" @default.
• W1994347680 cites W1500449111 @default.
• W1994347680 cites W1587888696 @default.
• W1994347680 cites W1969956936 @default.
• W1994347680 cites W1972708673 @default.
• W1994347680 cites W1977211716 @default.
• W1994347680 cites W1982908612 @default.
• W1994347680 cites W1989751879 @default.
• W1994347680 cites W2012793643 @default.
• W1994347680 cites W2022967427 @default.
• W1994347680 cites W2027631077 @default.
• W1994347680 cites W2034830092 @default.
• W1994347680 cites W2036908288 @default.
• W1994347680 cites W2041735112 @default.
• W1994347680 cites W2043280202 @default.
• W1994347680 cites W2059125981 @default.
• W1994347680 cites W2074664906 @default.
• W1994347680 cites W2077746984 @default.
• W1994347680 cites W2101748147 @default.
• W1994347680 cites W2137629638 @default.
• W1994347680 cites W2150934066 @default.
• W1994347680 cites W2199995433 @default.
• W1994347680 cites W2952206516 @default.
• W1994347680 cites W3137757896 @default.
• W1994347680 doi "https://doi.org/10.1039/dt9900002863" @default.
• W1994347680 hasPublicationYear "1990" @default.
• W1994347680 type Work @default.
• W1994347680 sameAs 1994347680 @default.
• W1994347680 citedByCount "18" @default.
• W1994347680 countsByYear W19943476802012 @default.
• W1994347680 countsByYear W19943476802013 @default.
• W1994347680 countsByYear W19943476802014 @default.
• W1994347680 countsByYear W19943476802020 @default.
• W1994347680 crossrefType "journal-article" @default.
• W1994347680 hasAuthorship W1994347680A5031287240 @default.
• W1994347680 hasAuthorship W1994347680A5036230982 @default.
• W1994347680 hasAuthorship W1994347680A5040355874 @default.
• W1994347680 hasAuthorship W1994347680A5054593712 @default.
• W1994347680 hasAuthorship W1994347680A5083086799 @default.
• W1994347680 hasAuthorship W1994347680A5091030530 @default.
• W1994347680 hasConcept C115624301 @default.
• W1994347680 hasConcept C116569031 @default.
• W1994347680 hasConcept C142724271 @default.
• W1994347680 hasConcept C161790260 @default.
• W1994347680 hasConcept C170493617 @default.
• W1994347680 hasConcept C178516000 @default.
• W1994347680 hasConcept C178790620 @default.
• W1994347680 hasConcept C185592680 @default.
• W1994347680 hasConcept C204787440 @default.
• W1994347680 hasConcept C2776910235 @default.
• W1994347680 hasConcept C2778818089 @default.
• W1994347680 hasConcept C55493867 @default.
• W1994347680 hasConcept C61276311 @default.
• W1994347680 hasConcept C71240020 @default.
• W1994347680 hasConcept C71924100 @default.
• W1994347680 hasConcept C8010536 @default.
• W1994347680 hasConceptScore W1994347680C115624301 @default.
• W1994347680 hasConceptScore W1994347680C116569031 @default.
• W1994347680 hasConceptScore W1994347680C142724271 @default.
• W1994347680 hasConceptScore W1994347680C161790260 @default.
• W1994347680 hasConceptScore W1994347680C170493617 @default.
• W1994347680 hasConceptScore W1994347680C178516000 @default.
• W1994347680 hasConceptScore W1994347680C178790620 @default.
• W1994347680 hasConceptScore W1994347680C185592680 @default.
• W1994347680 hasConceptScore W1994347680C204787440 @default.
• W1994347680 hasConceptScore W1994347680C2776910235 @default.
• W1994347680 hasConceptScore W1994347680C2778818089 @default.
• W1994347680 hasConceptScore W1994347680C55493867 @default.
• W1994347680 hasConceptScore W1994347680C61276311 @default.
• W1994347680 hasConceptScore W1994347680C71240020 @default.
• W1994347680 hasConceptScore W1994347680C71924100 @default.
• W1994347680 hasConceptScore W1994347680C8010536 @default.
• W1994347680 hasIssue "9" @default.
• W1994347680 hasLocation W19943476801 @default.
• W1994347680 hasOpenAccess W1994347680 @default.
• W1994347680 hasPrimaryLocation W19943476801 @default.
• W1994347680 hasRelatedWork W1973184772 @default.
• W1994347680 hasRelatedWork W2021157090 @default.
• W1994347680 hasRelatedWork W2062538232 @default.
• W1994347680 hasRelatedWork W2065204519 @default.
• W1994347680 hasRelatedWork W2084352656 @default.
• W1994347680 hasRelatedWork W2145413935 @default.
• W1994347680 hasRelatedWork W2149469070 @default.
• W1994347680 hasRelatedWork W2162519162 @default.
• W1994347680 hasRelatedWork W2312848220 @default.
• W1994347680 hasRelatedWork W4253811230 @default.
• W1994347680 isParatext "false" @default.
• W1994347680 isRetracted "false" @default.

• next