FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W1994361061> ?p ?o ?g. }

• W1994361061 endingPage "6221" @default.
• W1994361061 startingPage "6217" @default.
• W1994361061 abstract "We report the gas-phase photochlorination of methyl-terminated alkyl monolayers on silicon. We argue that this process proceeds by a free-radical mechanism, as is the case for homogeneous photochlorination. This is an example of what should be a family of convenient methods for the incorporation of various functional groups into simple alkyl monolayers by chlorine-radical activation. Monolayers prepared from 1-octadecene on Si(111) were exposed to Cl2 with illumination at 350 nm. We observe that a fraction of the carbon atoms on the surface become singly chlorinated and a smaller fraction become doubly chlorinated, as measured by the chemically shifted components of the C 1s X-ray photoelectron spectrum. The elemental composition of the resulting monolayers, film thickness, and contact angles are reported as a function of exposure. Under conditions that chlorinate only a fraction of the carbon atoms, IR spectroscopy reveals complete chlorination of the methyl groups, demonstrating a strong steric preference for chlorination at the ends of the alkyl chains. In the absence of illumination, a much slower dark reaction is observed." @default.
• W1994361061 created "2016-06-24" @default.
• W1994361061 creator A5006809109 @default.
• W1994361061 creator A5089597733 @default.
• W1994361061 date "2002-07-16" @default.
• W1994361061 modified "2023-09-27" @default.
• W1994361061 title "Surface Functionalization of Alkyl Monolayers by Free-Radical Activation: Gas-Phase Photochlorination with Cl₂" @default.
• W1994361061 cites W1481792836 @default.
• W1994361061 cites W1965894076 @default.
• W1994361061 cites W1966799682 @default.
• W1994361061 cites W1967598238 @default.
• W1994361061 cites W1969361334 @default.
• W1994361061 cites W1971809936 @default.
• W1994361061 cites W1972581015 @default.
• W1994361061 cites W1973902558 @default.
• W1994361061 cites W1977391735 @default.
• W1994361061 cites W1984796926 @default.
• W1994361061 cites W1991429779 @default.
• W1994361061 cites W1991615398 @default.
• W1994361061 cites W2000108966 @default.
• W1994361061 cites W2004200115 @default.
• W1994361061 cites W2006368131 @default.
• W1994361061 cites W2007229514 @default.
• W1994361061 cites W2008712026 @default.
• W1994361061 cites W2012959896 @default.
• W1994361061 cites W2013516496 @default.
• W1994361061 cites W2014811553 @default.
• W1994361061 cites W2022265330 @default.
• W1994361061 cites W2024534451 @default.
• W1994361061 cites W2026815334 @default.
• W1994361061 cites W2026853153 @default.
• W1994361061 cites W2027284371 @default.
• W1994361061 cites W2029015839 @default.
• W1994361061 cites W2030475165 @default.
• W1994361061 cites W2035691052 @default.
• W1994361061 cites W2046485345 @default.
• W1994361061 cites W2051987868 @default.
• W1994361061 cites W2052778580 @default.
• W1994361061 cites W2057026947 @default.
• W1994361061 cites W2057220750 @default.
• W1994361061 cites W2060548005 @default.
• W1994361061 cites W2072530426 @default.
• W1994361061 cites W2082597373 @default.
• W1994361061 cites W2087189171 @default.
• W1994361061 cites W2087617490 @default.
• W1994361061 cites W2088303745 @default.
• W1994361061 cites W2089349119 @default.
• W1994361061 cites W2091757785 @default.
• W1994361061 cites W2115432877 @default.
• W1994361061 cites W2120204945 @default.
• W1994361061 cites W2128439971 @default.
• W1994361061 cites W2132242391 @default.
• W1994361061 cites W2134819724 @default.
• W1994361061 cites W2160707406 @default.
• W1994361061 cites W2185386454 @default.
• W1994361061 cites W2298465447 @default.
• W1994361061 cites W2949627010 @default.
• W1994361061 cites W4241026414 @default.
• W1994361061 doi "https://doi.org/10.1021/la020095d" @default.
• W1994361061 hasPublicationYear "2002" @default.
• W1994361061 type Work @default.
• W1994361061 sameAs 1994361061 @default.
• W1994361061 citedByCount "38" @default.
• W1994361061 countsByYear W19943610612013 @default.
• W1994361061 countsByYear W19943610612015 @default.
• W1994361061 countsByYear W19943610612016 @default.
• W1994361061 countsByYear W19943610612019 @default.
• W1994361061 crossrefType "journal-article" @default.
• W1994361061 hasAuthorship W1994361061A5006809109 @default.
• W1994361061 hasAuthorship W1994361061A5089597733 @default.
• W1994361061 hasConcept C104779481 @default.
• W1994361061 hasConcept C115537861 @default.
• W1994361061 hasConcept C127413603 @default.
• W1994361061 hasConcept C140205800 @default.
• W1994361061 hasConcept C147789679 @default.
• W1994361061 hasConcept C159985019 @default.
• W1994361061 hasConcept C175708663 @default.
• W1994361061 hasConcept C178790620 @default.
• W1994361061 hasConcept C185592680 @default.
• W1994361061 hasConcept C192562407 @default.
• W1994361061 hasConcept C201194858 @default.
• W1994361061 hasConcept C2780263894 @default.
• W1994361061 hasConcept C42360764 @default.
• W1994361061 hasConcept C44280652 @default.
• W1994361061 hasConcept C55493867 @default.
• W1994361061 hasConcept C7070889 @default.
• W1994361061 hasConcept C71240020 @default.
• W1994361061 hasConcept C75473681 @default.
• W1994361061 hasConceptScore W1994361061C104779481 @default.
• W1994361061 hasConceptScore W1994361061C115537861 @default.
• W1994361061 hasConceptScore W1994361061C127413603 @default.
• W1994361061 hasConceptScore W1994361061C140205800 @default.
• W1994361061 hasConceptScore W1994361061C147789679 @default.
• W1994361061 hasConceptScore W1994361061C159985019 @default.
• W1994361061 hasConceptScore W1994361061C175708663 @default.
• W1994361061 hasConceptScore W1994361061C178790620 @default.
• W1994361061 hasConceptScore W1994361061C185592680 @default.
• W1994361061 hasConceptScore W1994361061C192562407 @default.

• next