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- W1994371073 endingPage "4406" @default.
- W1994371073 startingPage "4401" @default.
- W1994371073 abstract "[Ag4(L)4](PF6)4 and [Pd(L)2](PF6)2 (L = 3-(2,4-dimethyl-1,8-naphthyrid-7-yl)-1-picolylimidazolylidene) have been prepared and fully characterized. The silver compound consists of a Ag4 ring with short Ag−Ag contacts displaying a butterfly conformation. The palladium complex exhibits a helical structure with palladium located in a square-planar environment with two carbene ligands and two pyridines in a cis arrangement. The palladium complex has proven to be a highly efficient catalyst for Heck coupling reactions of aryl bromides with n-butyl acrylate. TON values up to 106 and TOF values up to 5 × 105 h−1 can be achieved." @default.
- W1994371073 created "2016-06-24" @default.
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- W1994371073 date "2008-08-06" @default.
- W1994371073 modified "2023-10-17" @default.
- W1994371073 title "Facile and Efficient Olefination of Aryl Halides Catalyzed by a Palladium Complex Containing a Heteroarene-Functionalized N-Heterocyclic Carbene" @default.
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- W1994371073 doi "https://doi.org/10.1021/om8003674" @default.
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