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- W1994375267 abstract "We present a complete study on four methane lines for two atmospheric micro-windows (in the ν2 + ν4 absorption band) used for the determination of atmospheric methane concentrations with ground-based Fourier transform spectrometers. Thanks to our tunable diode laser (TDL) spectrometer with active wavenumber control and step-by-step recording mode we have improved the accuracy on intensity, broadening, narrowing, and pressure shift parameters. To make our results directly useable in atmospheric models which usually assume a Voigt line shape, we have parameterised an effective-broadening parameter γVoigt (P) for each line and each gas mixture (CH4–N2 and CH4–O2). When this parameterisation is used to fit a “true” line profile, the same concentration as with more sophisticated models is retrieved using a consistent set of spectroscopic parameters in both approaches." @default.
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- W1994375267 date "2005-09-01" @default.
- W1994375267 modified "2023-09-27" @default.
- W1994375267 title "Line profile study by diode laser spectroscopy in the 12CH4 ν2+ν4 band" @default.
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- W1994375267 doi "https://doi.org/10.1016/j.jms.2005.05.012" @default.
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