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- W1994406380 abstract "The amphiphilic 3-oxodithiocarboxylic esters 2a-d have been prepared starting from p-hydroxy acetophenone. These esters react with transition metal salt MX2 (M Mn, Fe, Co, Ni, Pd, Pt, Cu, Zn; X Cl, OAc) to yield the tetrahedral and cis configurated square planar chelate complexes M(II) [SC(SR2)CHC(O)C6H4-p-OR1]2 (R1 = C6H13,C12H25; R2 = CH3,C6H13,C12H25) (3a-e, 5a-f, 6a-c) as well as the octahedral complexes py2M(II) [SC(SCH3)CHC(O)C6H4-p-OC6H13]2 (M = Mn, Fe) (4a,b) and fac-Co(III) [SC(SR2)CHC(O)C6H4-p-OC6H13]3 (R2 = CH3, C6H13) (7 and 8), respectively. The structures of 5c and 8 have been determined by single-crystal X-ray diffraction." @default.
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- W1994406380 date "1998-03-01" @default.
- W1994406380 modified "2023-10-04" @default.
- W1994406380 title "Synthesis and coordination properties of amphiphilic 3-oxodithiocarboxylic esters" @default.
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- W1994406380 doi "https://doi.org/10.1016/s0020-1693(97)05881-7" @default.
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