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• W1994421816 abstract "The melting behaviour, solid state phase transformations, structure and magnetic properties of pseudo-ternary compounds Nd2(Fe1 − xNix)14B and Pr2(Co1 − yNiy)14B have been studied using differential thermal analysis, optical microscopy, X-ray diffraction, electron probe micro-analysis and magnetic measurements. It was found that the Curie temperature of Nd2(Fe1 − xNix)14B increased with increasing x up to x = 0.2, however the saturation magnetization behaved in an opposite way. In the case of Pr2(Co1 − yNiy)14B, the Curie temperature decreased with increasing y up to y = 0.2. The magnetic phase transition occurring at a temperature between room temperature and Curie temperature is believed to be associated with spin reorientation. The magnetic phase transition temperature is lowered by nickel substitution. At high temperature, eutectoid decomposition R2(Ni, M)17 → R(Ni, M)5 + α-Ni(M) takes place in these two pseudo-ternary compounds in the composition ranges x = 0.6 – 1.0 and y = 0.3 – 1.0 respectively. When x(y)⩽0.2, both Nd2(Fe1 − xNix)14B and Pr2(Co1 − yNiy)14B are single phase with a tetragonal structure. The phase constituents of these two systems at room temperature are triplex in the composition range 0.3⩽x(y)⩽1.0." @default.
• W1994421816 created "2016-06-24" @default.
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• W1994421816 date "1988-12-01" @default.
• W1994421816 modified "2023-10-16" @default.
• W1994421816 title "Structure and magnetic properties of R2(M, Ni)14B pseudoternary compounds (R ≡ Nd, Pr; M ≡ Fe, Co)" @default.
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• W1994421816 doi "https://doi.org/10.1016/0022-5088(88)90137-3" @default.
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