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- W1994463433 abstract "Abstract Complex formation between Zn(II) ion and 1,2-ethanediamine (en) or 2-aminoethylammonium cation (enH+) has been studied in 3 M (Na,H)ClO4 at 25°, by measuring the e.m.f. of glass and Zn(Hg) electrodes. At low initial acid concentration range and relatively high initial Zn(II) concentration the formation of a precipitate (for n < 1.9) was observed. From e.m.f. measurements of the solutions with high initial 1,2-ethane-diammonium diperchlorate concentrations (CenH2(ClO4)2 =0.75 or 0.50 M) and a low initial Zn(II) concentration (CZn(ClO4)2 =4.79 × 10−3 M) the values for the cumulative stability constants of the following complexes were evaluated: Zn(en)2+, β10=106.49±0.02; Zn(en)2 2+, β20=1012.44±0.01; Zn(en)3 2+, β30=1014.88±0.12; Zn(enH)3+, β01=101.03±0.06; Zn(en)(enH)3+, β11=107.47±0.13; Zn(en)2(enH)3+, β21=1012.81±0.03." @default.
- W1994463433 created "2016-06-24" @default.
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- W1994463433 date "1985-05-01" @default.
- W1994463433 modified "2023-10-14" @default.
- W1994463433 title "STABILITY CONSTANTS OF PROTONATED NON-AND PARTLY-CHELATED COMPLEXES IN THE ZINC 1,2-ETHANEDIAMINE SYSTEM" @default.
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- W1994463433 doi "https://doi.org/10.1080/00958978508080676" @default.
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