Matches in SemOpenAlex for { <https://semopenalex.org/work/W1994471588> ?p ?o ?g. }
Showing items 1 to 92 of
92
with 100 items per page.
- W1994471588 endingPage "1556" @default.
- W1994471588 startingPage "1545" @default.
- W1994471588 abstract "Reactions between a series bidentate phosphines, with the general formula PPh2(CH2)nPPh2, and the air stable hexaborane(10) analogue [2,2,2-(PPh3)2(CO)-nido-2-OsB5H9] (1), afford species of the type [{(PPh3)2(CO)OsB4H7}-3-{BH2PPh2(CH2)n(PPh2)}] (2) which contain a pendent PPh2 group. In solution 2 can undergo an intramolecular substitution reaction to form the species [{(PPh3)(CO)OsB4H7}-η2-3,2-{BH2PPh2(CH2)n(PPh2)}] (4). In spite of this, chemistry at the pendent PPh2 group may be studied and herein are reported the results of reactions of 2 with the organometallic reagent [(p-cym)RuX2]2 (X = Cl, I) to afford hybrid bimetallaborane clusters of the type [2,2,2-(PPh3)2(CO)-nido-2-OsB4H7-3-(BH2PPh2)CxHyPPh2RuCl2(p-cym)] (5) The species obtained include [2,2,2-(PPh3)2(CO)-nido-2-OsB4H7 · 3-(BH2 · dppe · Ru(p-cym)Cl2)] (5a), [2,2,2-(PPh3)2(CO)-nido-2-OsB4H7 · 3-(BH2 · dppp · Ru(p-cym)Cl2)] (5b), [2,2,2-(PPh3)2(CO)-2-nido-OsB4H7 · 3-(BH2 · dpph · Ru(p-cym)Cl2)] (5c), [2,2,2-(PPh3)2(CO)-nido-2-OsB4H7-3-(BH2 · dppx · Ru(p-cym)Cl2)] (5d) and [2,2,2-(PPh3)2(CO)-nido-2-OsB4H7-3-(BH2 · dppe · Ru(p- cym)I2)] (6). Species 5d was also prepared from the reaction between 1 and the known compound · [dppx · Ru(p-cym)Cl2. Species 5a–5d and 6 were characterized by elemental analysis, high resolution mass spectrometry and NMR spectrometry; the latter affording some novel features for this series of compounds. Structure determination by X-ray diffraction was not successful but a structure of the analogue [BH3 · (PPh2)(CH2)6(PPh2) · Ru(p-cym)Cl2] (7) is reported." @default.
- W1994471588 created "2016-06-24" @default.
- W1994471588 creator A5001482204 @default.
- W1994471588 creator A5050210292 @default.
- W1994471588 creator A5056651115 @default.
- W1994471588 creator A5090691510 @default.
- W1994471588 date "2005-03-01" @default.
- W1994471588 modified "2023-09-26" @default.
- W1994471588 title "Degradation and modification of metallaboranes. Part 4: Synthesis and characterization of a series of hybrid bimetallaborane clusters of the type [2,2,2-(PPh3)2(CO)-nido-2-OsB4H7-3-(BH2PPh2)CxHyPPh2RuCl2(p-cym)]" @default.
- W1994471588 cites W13532363 @default.
- W1994471588 cites W1440179546 @default.
- W1994471588 cites W1532684710 @default.
- W1994471588 cites W1714241231 @default.
- W1994471588 cites W1968849293 @default.
- W1994471588 cites W1976139910 @default.
- W1994471588 cites W1981538646 @default.
- W1994471588 cites W1997373095 @default.
- W1994471588 cites W1997631581 @default.
- W1994471588 cites W2008540481 @default.
- W1994471588 cites W2011589200 @default.
- W1994471588 cites W2016296610 @default.
- W1994471588 cites W2029852148 @default.
- W1994471588 cites W2031364714 @default.
- W1994471588 cites W2033708796 @default.
- W1994471588 cites W2043707232 @default.
- W1994471588 cites W2045399620 @default.
- W1994471588 cites W2048758576 @default.
- W1994471588 cites W2050703174 @default.
- W1994471588 cites W2072869918 @default.
- W1994471588 cites W2084739895 @default.
- W1994471588 cites W2088962271 @default.
- W1994471588 cites W2144332006 @default.
- W1994471588 cites W2166223379 @default.
- W1994471588 cites W2319122936 @default.
- W1994471588 cites W2324670438 @default.
- W1994471588 cites W2328006678 @default.
- W1994471588 cites W2328857150 @default.
- W1994471588 cites W304678273 @default.
- W1994471588 cites W1993724373 @default.
- W1994471588 doi "https://doi.org/10.1016/j.ica.2004.10.015" @default.
- W1994471588 hasPublicationYear "2005" @default.
- W1994471588 type Work @default.
- W1994471588 sameAs 1994471588 @default.
- W1994471588 citedByCount "4" @default.
- W1994471588 crossrefType "journal-article" @default.
- W1994471588 hasAuthorship W1994471588A5001482204 @default.
- W1994471588 hasAuthorship W1994471588A5050210292 @default.
- W1994471588 hasAuthorship W1994471588A5056651115 @default.
- W1994471588 hasAuthorship W1994471588A5090691510 @default.
- W1994471588 hasConcept C115624301 @default.
- W1994471588 hasConcept C155647269 @default.
- W1994471588 hasConcept C161790260 @default.
- W1994471588 hasConcept C178516000 @default.
- W1994471588 hasConcept C178790620 @default.
- W1994471588 hasConcept C185592680 @default.
- W1994471588 hasConcept C40875361 @default.
- W1994471588 hasConcept C555196967 @default.
- W1994471588 hasConcept C71240020 @default.
- W1994471588 hasConcept C75079739 @default.
- W1994471588 hasConcept C8010536 @default.
- W1994471588 hasConceptScore W1994471588C115624301 @default.
- W1994471588 hasConceptScore W1994471588C155647269 @default.
- W1994471588 hasConceptScore W1994471588C161790260 @default.
- W1994471588 hasConceptScore W1994471588C178516000 @default.
- W1994471588 hasConceptScore W1994471588C178790620 @default.
- W1994471588 hasConceptScore W1994471588C185592680 @default.
- W1994471588 hasConceptScore W1994471588C40875361 @default.
- W1994471588 hasConceptScore W1994471588C555196967 @default.
- W1994471588 hasConceptScore W1994471588C71240020 @default.
- W1994471588 hasConceptScore W1994471588C75079739 @default.
- W1994471588 hasConceptScore W1994471588C8010536 @default.
- W1994471588 hasIssue "5" @default.
- W1994471588 hasLocation W19944715881 @default.
- W1994471588 hasOpenAccess W1994471588 @default.
- W1994471588 hasPrimaryLocation W19944715881 @default.
- W1994471588 hasRelatedWork W2007733004 @default.
- W1994471588 hasRelatedWork W2023214535 @default.
- W1994471588 hasRelatedWork W2038115888 @default.
- W1994471588 hasRelatedWork W2049611623 @default.
- W1994471588 hasRelatedWork W2078322288 @default.
- W1994471588 hasRelatedWork W2094952541 @default.
- W1994471588 hasRelatedWork W2096306259 @default.
- W1994471588 hasRelatedWork W2329427790 @default.
- W1994471588 hasRelatedWork W2898352696 @default.
- W1994471588 hasRelatedWork W2950101911 @default.
- W1994471588 hasVolume "358" @default.
- W1994471588 isParatext "false" @default.
- W1994471588 isRetracted "false" @default.
- W1994471588 magId "1994471588" @default.
- W1994471588 workType "article" @default.