Matches in SemOpenAlex for { <https://semopenalex.org/work/W1994501401> ?p ?o ?g. }
Showing items 1 to 86 of
86
with 100 items per page.
- W1994501401 endingPage "94" @default.
- W1994501401 startingPage "88" @default.
- W1994501401 abstract "Water can displace cyclohexane from chemisorption sites on a Ru(001) surface. In so doing, thermal desorption spectroscopy indicates that the water forms three-dimensional, hydrogenbonded clusters which are two layers deep, much as it would on the clean surface. Water forces the cyclohexane into weakly bound states. This is apparently driven by a combination of effects: first, a single water molecule is more strongly bound to the ruthenium surface than a cyclohexane molecule and second, the packing density of water in the hydrogen-bonded bilayer is much greater than the packing density of the chemisorbed cyclohexane. Taking both effects into consideration, replacement of a chemisorbed cyclohexane layer with a water bilayer is energetically favored by 5 to 8 kcal per mole of surface metal atoms. The data also show that the preferential chemisorption of water on ruthenium is not limited by the kinetics of diffusion or displacement in these experiments, but rather reflects a true equilibrium state." @default.
- W1994501401 created "2016-06-24" @default.
- W1994501401 creator A5042401569 @default.
- W1994501401 creator A5047326836 @default.
- W1994501401 creator A5060961404 @default.
- W1994501401 date "1986-05-01" @default.
- W1994501401 modified "2023-09-23" @default.
- W1994501401 title "Displacement of cyclohexane by water on a ruthenium surface" @default.
- W1994501401 cites W1532532470 @default.
- W1994501401 cites W1573051457 @default.
- W1994501401 cites W2019412232 @default.
- W1994501401 cites W2031145202 @default.
- W1994501401 cites W2045587339 @default.
- W1994501401 cites W2057407067 @default.
- W1994501401 cites W2062665814 @default.
- W1994501401 cites W2081973080 @default.
- W1994501401 cites W2082706658 @default.
- W1994501401 cites W2084036209 @default.
- W1994501401 cites W2105586031 @default.
- W1994501401 cites W2061135482 @default.
- W1994501401 doi "https://doi.org/10.1016/0021-9517(86)90201-0" @default.
- W1994501401 hasPublicationYear "1986" @default.
- W1994501401 type Work @default.
- W1994501401 sameAs 1994501401 @default.
- W1994501401 citedByCount "21" @default.
- W1994501401 crossrefType "journal-article" @default.
- W1994501401 hasAuthorship W1994501401A5042401569 @default.
- W1994501401 hasAuthorship W1994501401A5047326836 @default.
- W1994501401 hasAuthorship W1994501401A5060961404 @default.
- W1994501401 hasConcept C147789679 @default.
- W1994501401 hasConcept C150394285 @default.
- W1994501401 hasConcept C159467904 @default.
- W1994501401 hasConcept C161790260 @default.
- W1994501401 hasConcept C162711632 @default.
- W1994501401 hasConcept C178790620 @default.
- W1994501401 hasConcept C185592680 @default.
- W1994501401 hasConcept C192157962 @default.
- W1994501401 hasConcept C2778237882 @default.
- W1994501401 hasConcept C32909587 @default.
- W1994501401 hasConcept C33790079 @default.
- W1994501401 hasConcept C41625074 @default.
- W1994501401 hasConcept C512968161 @default.
- W1994501401 hasConcept C55493867 @default.
- W1994501401 hasConcept C555196967 @default.
- W1994501401 hasConcept C73673656 @default.
- W1994501401 hasConcept C75473681 @default.
- W1994501401 hasConcept C8010536 @default.
- W1994501401 hasConceptScore W1994501401C147789679 @default.
- W1994501401 hasConceptScore W1994501401C150394285 @default.
- W1994501401 hasConceptScore W1994501401C159467904 @default.
- W1994501401 hasConceptScore W1994501401C161790260 @default.
- W1994501401 hasConceptScore W1994501401C162711632 @default.
- W1994501401 hasConceptScore W1994501401C178790620 @default.
- W1994501401 hasConceptScore W1994501401C185592680 @default.
- W1994501401 hasConceptScore W1994501401C192157962 @default.
- W1994501401 hasConceptScore W1994501401C2778237882 @default.
- W1994501401 hasConceptScore W1994501401C32909587 @default.
- W1994501401 hasConceptScore W1994501401C33790079 @default.
- W1994501401 hasConceptScore W1994501401C41625074 @default.
- W1994501401 hasConceptScore W1994501401C512968161 @default.
- W1994501401 hasConceptScore W1994501401C55493867 @default.
- W1994501401 hasConceptScore W1994501401C555196967 @default.
- W1994501401 hasConceptScore W1994501401C73673656 @default.
- W1994501401 hasConceptScore W1994501401C75473681 @default.
- W1994501401 hasConceptScore W1994501401C8010536 @default.
- W1994501401 hasIssue "1" @default.
- W1994501401 hasLocation W19945014011 @default.
- W1994501401 hasOpenAccess W1994501401 @default.
- W1994501401 hasPrimaryLocation W19945014011 @default.
- W1994501401 hasRelatedWork W1528479865 @default.
- W1994501401 hasRelatedWork W1979447167 @default.
- W1994501401 hasRelatedWork W1981861356 @default.
- W1994501401 hasRelatedWork W1984903653 @default.
- W1994501401 hasRelatedWork W1993205302 @default.
- W1994501401 hasRelatedWork W1993342114 @default.
- W1994501401 hasRelatedWork W2041281679 @default.
- W1994501401 hasRelatedWork W2046030772 @default.
- W1994501401 hasRelatedWork W2048623558 @default.
- W1994501401 hasRelatedWork W2069146223 @default.
- W1994501401 hasVolume "99" @default.
- W1994501401 isParatext "false" @default.
- W1994501401 isRetracted "false" @default.
- W1994501401 magId "1994501401" @default.
- W1994501401 workType "article" @default.