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- W1994501478 abstract "Luminescent silver nanocrystals (L-AgNCs) were synthesized using an amphiphilic polymer template, consisting of dodecylamine (DDA) grafted poly(acrylic acid) (PAA). Upon UV-light irradiation at 365 nm for different time intervals, AgNCs were gradually achieved and exhibited distinct luminescence. After undergoing 1.5 h irradiation, the maximum emission peak of L-AgNCs was located at 612 nm. In addition, the resulting L-AgNCs possessed pH-triggered phase transfer from water to chloroform. When adjusting pH of buffer solutions contained L-AgNCs from 5.0 toward 4.0, the hydrophilic AgNCs gradually became hydrophobic, together with a significant transfer from H 2 O phase to chloroform phase. This design could be further developed toward a smart luminescence imaging reagent, or therapeutic nanoparticles with controllable solubility by a small pH change. ► Luminescent silver nanocrystals (L-AgNCs) were synthesized using an amphiphilic polymer-template. ► The synthesis was based on UV-irradiation reduction reaction in aqueous solution. ► The resulting L-AgNCs exhibit pH-triggered phase transfer. ► The phase transfer occurred between pH 4 and 5." @default.
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- W1994501478 date "2013-04-01" @default.
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- W1994501478 title "Amphiphilic polymer-template synthesis and pH-triggered phase transfer of luminescent silver nanocrystals" @default.
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- W1994501478 doi "https://doi.org/10.1016/j.matlet.2013.01.005" @default.
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