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• W1994501782 startingPage "99" @default.
• W1994501782 abstract "The unimolecular chemistry of CH3ReO+3 in the gas phase commences with a methyl migration to' generate CH3 OReO+2. This further undergoes multiple hydrogen migration to the metal centre to generate an intermediate which serves as a precursor for the elimination of both molecular hydrogen and of carbon monoxide. If CH3ReO+3 is reacted with ethylene, inter alia products are observed which point to a competition between an intramolecular metathesis reaction of the ethylene-inserted intermediate CH3CH2CH2ReO3+ and epoxidation of ethylene to generate c-C2H4O." @default.
• W1994501782 created "2016-06-24" @default.
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• W1994501782 date "1992-12-01" @default.
• W1994501782 modified "2023-10-09" @default.
• W1994501782 title "Unimolecular fragrmentations of the radical cation of the high-valent organometal oxide CH3ReO3 and its reactivity with ethylene in the gas phase" @default.
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• W1994501782 doi "https://doi.org/10.1016/0168-1176(92)87010-c" @default.
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