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- W1994509923 abstract "Die Mandel-Samenschale enthält im unverseifbaren Anteil ihres fetten Öls neben sieben Sterolen, die bereits vom Mandel-Samenöl her bekannt sind, noch 24-Methylen-cholesterol (6), Fucosterol (8) und je einen Glucopyranosylether von Sitosterol und Stigmasterol. Campesterol tritt im Schalenöl in achtmal höherer Konzentration als im Samenöl auf. Gesättigte Sterole lagen nicht vor. Dies wurde durch Oxidation der Fraktion der einfach ungesättigten Sterole nach Jones bewiesen. Neben den zu erwartenden Oxidationsprodukten ließen sich noch (24R)-Stigmast-5-en-3β-yl-formiat (10) und (24R)-Stigmast-5-en-3-on-dimethylacetal (11) nachweisen. Beide Steroide dürften Artefacte sein. Sterols of Almond Seed Coat Additionally to seven sterols known from the almond seed oil the nonsaponifiable part of the greasy oil of almond seed coats contains 24-methylencholesterol (6), fucosterol (8) and sitosterol and stigmasterol glucopyranosyl ethers. The campesterol concentration was eight fold compared to the seed oil. Saturated sterols were not present proved after Jones oxidation of the monounsaturated sterol fraction. Amongst the expected oxidation products (24R)-stigmast-5-en-3β-yl formiate (10) and (24R)-stigmast-5-en-3-on dimethylacetal (11) have been identified, which both should be artefacts." @default.
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- W1994509923 date "1987-01-01" @default.
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- W1994509923 title "Die Steroide der Mandel-Samenschale" @default.
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- W1994509923 doi "https://doi.org/10.1002/lipi.19870890607" @default.
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