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- W1994529892 abstract "Spin Trapping Investigations on the Behaviour of the Pentacarbonyl Rhenium RadicalBoth ·Re(CO)5 and ·Re2(CO)9⊕ radicals have been spin-trapped by nitroso compounds during the photolysis of [Re2(CO)10] at room temperature in CH2Cl2 solution. Interaction with nucleophiles Nu, such as pyridine, PPh3, AsPh3, and SbPh3, led to ·Re(CO)4Nu radicals. Although only ·Re(CO)4PPh3 gave a persistent spin adduct with nitrosodurene, the formation of the other substitution products was evidenced by their increased reactivity towards carbon halides. In the presence of dioxygen, superoxide is formed and trapped." @default.
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- W1994529892 date "1989-01-01" @default.
- W1994529892 modified "2023-09-26" @default.
- W1994529892 title "Spintrapping-Untersuchungen zum Verhalten des Pentacarbonylrhenium-Radikals" @default.
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- W1994529892 doi "https://doi.org/10.1002/prac.19893310512" @default.
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