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• W1994534051 startingPage "4708" @default.
• W1994534051 abstract "The complete absolute configuration of hormaomycin 1 a has been established by HPLC and HPLC/MS experiments with appropriately derivatized 4-propylprolines, (2S,4S)-6 and (2R,4R)-6, as well as 4-(Z)-propenylprolines, cis-5 and trans-5, and also feeding experiments with enantiomerically pure samples of the deuterium-labeled 3-(2'-nitrocyclopropyl)alanine, (2S)-3,3-[D2]15 and (2S)-2,2'-[D2]15, and 4-(Z)-propenylproline 2',4-[D2]-(2S,4R)-5. The latter five amino acids were prepared for the first time and allowed one to unequivocally assign the hitherto unknown absolute configurations of the last four stereocenters in hormaomycin 1 a. As a bonus, some new information about the biosynthesis of this molecule has also been gathered." @default.
• W1994534051 created "2016-06-24" @default.
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• W1994534051 date "2004-09-22" @default.
• W1994534051 modified "2023-10-11" @default.
• W1994534051 title "Final Elucidation of the Absolute Configuration of the Signal Metabolite Hormaomycin" @default.
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• W1994534051 doi "https://doi.org/10.1002/chem.200400406" @default.
• W1994534051 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/15372686" @default.
• W1994534051 hasPublicationYear "2004" @default.
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