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• W1994540516 abstract "The laser-induced fluorescence (LIF) excitation spectrum of the A 2A1 ← X 2E band system of the CH3O radical has been studied at both low (≈ 10 cm−1) and high (≈ 0.1 cm−1) resolution. CH3O radicals were generated in a discharge flow system via the reaction F + CH3OH → CH3O + HF. Low-resolution excitation spectra were dominated by a progression 30n in the upper state CO stretch vibration ν′3 in agreement with earlier findings reported in the literature. The previously questioned vibrational band assignment was ascertained by comparing fundamental and hot band intensities as a function of temperature. Rotationally resolved excitation scans were performed for the 000 band. A 50 cm−1 wide portion towards the less congested blue side of this band was rotationally assigned. A least-squares fit to the observed line positions yielded precise values of the A-state electronic origin and the rotational constants. After removal of the X-state spin-orbit splitting the value for the origin is T0 = 31613.9 ± 0.5 cm−1." @default.
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• W1994540516 date "1989-04-01" @default.
• W1994540516 modified "2023-09-23" @default.
• W1994540516 title "Rotationally resolved laser-induced fluorescence excitation studies of CH3O" @default.
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• W1994540516 doi "https://doi.org/10.1016/0301-0104(89)80088-6" @default.
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