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- W1994560436 abstract "Propene polymerization using homogeneous methylalumoxane (MAO)-activated rac-Me2Si(2-Me-Benz[e]Ind)2ZrCl2 was studied as a function of both metallocene and MAO concentration. At 40 °C and 2 bar propene pressure in toluene the catalyst activities and poly(propene) molecular weights depend upon the MAO concentration, whereas the zirconium concentration of the [Al]/[Zr] molar ratios are much less significant. At high MAO concentrations, MAO competes with propene for vacant coordination sites, thus adversely affecting catalyst activity. Optimum performance in terms of catalyst activity and molecular weight was obtained at an MAO concentration with [Al] = 5 mmol l−1." @default.
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- W1994560436 date "1995-07-01" @default.
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- W1994560436 title "The influence of methylalumoxane concentration on propene polymerization with homogeneous metallocene-based Ziegler-Natta catalysts" @default.
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- W1994560436 doi "https://doi.org/10.1016/0022-328x(95)00106-z" @default.
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