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• W1994564304 abstract "Thin overlayers of Na, K, Rb, and Cs on different $mathrm{sp}$-metal substrates have been investigated using photoelectron spectroscopy. The alkali core levels show clearly resolved binding-energy shifts between the surface layer, the intermediate layer(s), and the interface layer. The magnitude of these shifts depends on $mathrm{sp}$ metal and on alkali metal. The layer-resolved core-level binding-energy shifts are well reproduced by models based on a thermodynamical description. For three-layer alkali films the core-level binding energy of the intermediate layer is found to exhibit a small but significant shift between different $mathrm{sp}$-metal substrates. A simple relationship between the core-level binding-energy shift for the interface layer and the difference in ${r}_{s}$ value between the $mathrm{sp}$ substrate and the adsorbate is shown to exist." @default.
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• W1994564304 date "1997-11-15" @default.
• W1994564304 modified "2023-09-23" @default.
• W1994564304 title "Unified behavior of alkali core-level binding-energy shifts induced byspmetals" @default.
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• W1994564304 doi "https://doi.org/10.1103/physrevb.56.12560" @default.
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