FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W1994569112> ?p ?o ?g. }

• W1994569112 endingPage "2775" @default.
• W1994569112 startingPage "2769" @default.
• W1994569112 abstract "A new titanium hexanuclear oxo carboxylato alkoxide complex, with the general formula [Ti6O6(OPri)6(OOCBut)6] (1), has been synthesized in a reaction of titanium isopropoxide (Ti(OPri)4) with ButCOOH in the ratio 1:1. The structure was analyzed with the elemental analysis, IR and NMR spectroscopy, and X-ray single-crystal diffraction methods. Crystal structure of 1 was solved in the trigonal centrosymmetric system R3̄r. Titanium atoms form the hexanuclear cluster, where three μ3-oxo, two μ-carboxylato bridges and the terminal alkoxide ligand, in the distorted octahedron, surround each central cation. Analysis of spectroscopic data revealed a significant nonequivalence of interactions formed by the carboxylate groups, resulting from the asymmetry of Ti-μ-OOC bonds of carboxylate bridges in the complex molecule. TGA and MS studies suggest that volatile, titanium hexanuclear species may be formed between 423 and 553 K." @default.
• W1994569112 created "2016-06-24" @default.
• W1994569112 creator A5026888386 @default.
• W1994569112 creator A5073145425 @default.
• W1994569112 creator A5075784588 @default.
• W1994569112 creator A5087790009 @default.
• W1994569112 date "2004-07-01" @default.
• W1994569112 modified "2023-09-27" @default.
• W1994569112 title "Structural and thermal stability studies of Ti(IV) hexanuclear oxo trimethylacetato isopropoxide complex" @default.
• W1994569112 cites W153159988 @default.
• W1994569112 cites W1710565104 @default.
• W1994569112 cites W1974791136 @default.
• W1994569112 cites W1991331491 @default.
• W1994569112 cites W1992849898 @default.
• W1994569112 cites W1997921153 @default.
• W1994569112 cites W2008294851 @default.
• W1994569112 cites W2010370149 @default.
• W1994569112 cites W2045846028 @default.
• W1994569112 cites W2053535968 @default.
• W1994569112 cites W2078982026 @default.
• W1994569112 cites W2080406736 @default.
• W1994569112 cites W2084876578 @default.
• W1994569112 cites W2087491964 @default.
• W1994569112 cites W2089077097 @default.
• W1994569112 cites W2132411137 @default.
• W1994569112 cites W2952876921 @default.
• W1994569112 doi "https://doi.org/10.1016/j.ica.2004.02.022" @default.
• W1994569112 hasPublicationYear "2004" @default.
• W1994569112 type Work @default.
• W1994569112 sameAs 1994569112 @default.
• W1994569112 citedByCount "36" @default.
• W1994569112 countsByYear W19945691122012 @default.
• W1994569112 countsByYear W19945691122013 @default.
• W1994569112 countsByYear W19945691122014 @default.
• W1994569112 countsByYear W19945691122015 @default.
• W1994569112 countsByYear W19945691122016 @default.
• W1994569112 countsByYear W19945691122017 @default.
• W1994569112 countsByYear W19945691122018 @default.
• W1994569112 countsByYear W19945691122019 @default.
• W1994569112 countsByYear W19945691122020 @default.
• W1994569112 countsByYear W19945691122021 @default.
• W1994569112 countsByYear W19945691122023 @default.
• W1994569112 crossrefType "journal-article" @default.
• W1994569112 hasAuthorship W1994569112A5026888386 @default.
• W1994569112 hasAuthorship W1994569112A5073145425 @default.
• W1994569112 hasAuthorship W1994569112A5075784588 @default.
• W1994569112 hasAuthorship W1994569112A5087790009 @default.
• W1994569112 hasConcept C115624301 @default.
• W1994569112 hasConcept C116569031 @default.
• W1994569112 hasConcept C153642686 @default.
• W1994569112 hasConcept C161790260 @default.
• W1994569112 hasConcept C164866538 @default.
• W1994569112 hasConcept C170493617 @default.
• W1994569112 hasConcept C178790620 @default.
• W1994569112 hasConcept C185592680 @default.
• W1994569112 hasConcept C198819137 @default.
• W1994569112 hasConcept C199360897 @default.
• W1994569112 hasConcept C2778074193 @default.
• W1994569112 hasConcept C2778839380 @default.
• W1994569112 hasConcept C32909587 @default.
• W1994569112 hasConcept C41008148 @default.
• W1994569112 hasConcept C506065880 @default.
• W1994569112 hasConcept C55493867 @default.
• W1994569112 hasConcept C71240020 @default.
• W1994569112 hasConcept C8010536 @default.
• W1994569112 hasConceptScore W1994569112C115624301 @default.
• W1994569112 hasConceptScore W1994569112C116569031 @default.
• W1994569112 hasConceptScore W1994569112C153642686 @default.
• W1994569112 hasConceptScore W1994569112C161790260 @default.
• W1994569112 hasConceptScore W1994569112C164866538 @default.
• W1994569112 hasConceptScore W1994569112C170493617 @default.
• W1994569112 hasConceptScore W1994569112C178790620 @default.
• W1994569112 hasConceptScore W1994569112C185592680 @default.
• W1994569112 hasConceptScore W1994569112C198819137 @default.
• W1994569112 hasConceptScore W1994569112C199360897 @default.
• W1994569112 hasConceptScore W1994569112C2778074193 @default.
• W1994569112 hasConceptScore W1994569112C2778839380 @default.
• W1994569112 hasConceptScore W1994569112C32909587 @default.
• W1994569112 hasConceptScore W1994569112C41008148 @default.
• W1994569112 hasConceptScore W1994569112C506065880 @default.
• W1994569112 hasConceptScore W1994569112C55493867 @default.
• W1994569112 hasConceptScore W1994569112C71240020 @default.
• W1994569112 hasConceptScore W1994569112C8010536 @default.
• W1994569112 hasIssue "9" @default.
• W1994569112 hasLocation W19945691121 @default.
• W1994569112 hasOpenAccess W1994569112 @default.
• W1994569112 hasPrimaryLocation W19945691121 @default.
• W1994569112 hasRelatedWork W1013836473 @default.
• W1994569112 hasRelatedWork W2016430179 @default.
• W1994569112 hasRelatedWork W2057760728 @default.
• W1994569112 hasRelatedWork W2088061617 @default.
• W1994569112 hasRelatedWork W2157182592 @default.
• W1994569112 hasRelatedWork W2314348767 @default.
• W1994569112 hasRelatedWork W2387323779 @default.
• W1994569112 hasRelatedWork W3133086923 @default.
• W1994569112 hasRelatedWork W3195928975 @default.
• W1994569112 hasRelatedWork W2091681328 @default.
• W1994569112 hasVolume "357" @default.

• next