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- W1994574106 abstract "Complete vibrational assignments of the complexes [Cl2Pt(C5H8)]2, [Br2Pt(C5H8)]2, [Cl2Pd(C5H8)]2 and [Br2Pd(C5H8)]2 have been undertaken from 1500 to 70 cm−1. A reinvestigation of the cyclopentene spectrum was necessary and a new set of assignments is given. The v(CC) shifts down about 200 cm−1 for all the complexes and represents the largest shift observed for a Pd-mono-olefln complex. The shifts observed for the cyclopentene vibrations upon complexation as well as the fact that there are two platinum-carbon stretching frequencies but only one palladium-carbon stretching frequency is consistent with a strong π interaction in the platinum complexes leading to a bonding scheme and a predominantly σ interaction in the palladium complexes with the bonding scheme being the best description. It appears, however, that the total interaction, i.e. σ + π, is about the same in the complexes studied." @default.
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- W1994574106 date "1973-07-01" @default.
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- W1994574106 title "A vibrational investigation of several platinum and palladium cyclopentene complexes" @default.
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- W1994574106 doi "https://doi.org/10.1016/0584-8539(73)80207-7" @default.
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