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• W1994588780 abstract "Abstract Towards a molecular understanding of the mechanism behind catalytic reforming of bioderived hydrocarbon oxygenates, we explore the CC bond scission of C 2 model compounds (acetic acid, ethanol, ethylene glycol) on ceria model catalysts of different complexity, with and without platinum. Synchrotron photoelectron spectroscopy reveals that the reaction pathway depends very specifically on both the reactant molecule and the catalyst surface. Whereas CC bond scission on Pt sites and on oxygen vacancies involves intermittent surface carbon species, the reaction occurs without any carbon formation and deposition for ethylene glycol on CeO 2 (111)." @default.
• W1994588780 created "2016-06-24" @default.
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• W1994588780 date "2013-11-06" @default.
• W1994588780 modified "2023-10-18" @default.
• W1994588780 title "The Mechanism of Hydrocarbon Oxygenate Reforming: CC Bond Scission, Carbon Formation, and Noble-Metal-Free Oxide Catalysts" @default.
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• W1994588780 doi "https://doi.org/10.1002/cssc.201301000" @default.
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