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- W1994593113 abstract "Abstract A series of functionalized mesoporous silicas with cagelike pore topology has been synthesized and screened for size‐selective catalytic transformations. The aluminum‐catalyzed Meerwein–Ponndorf–Verley (MPV) reduction of differently sized aromatic aldehydes (benzaldehyde and 1‐pyrenecarbox‐aldehyde) has been investigated as a test reaction. The catalysts were synthesized in a two‐step grafting sequence comprising pore‐size engineering of mesoporous silicas (SBA‐1, SBA‐2, SBA‐16) with long‐chain alkyl dimethylaminosilanes and surface organoaluminum chemistry with triethylaluminum [{Al(CH 2 CH 3 ) 3 } 2 ]. Size‐selective reaction behavior was found for small pore SBA‐1 materials, and the selectivity could be efficiently tuned by selecting a silylating reagent of appropriate size. The results are compared with the catalytic performance of a large‐pore periodic mesoporous organosilica PMO[SBA‐1] and the nonporous high‐surface‐area silicas Aerosil 300/380." @default.
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- W1994593113 date "2007-03-23" @default.
- W1994593113 modified "2023-10-14" @default.
- W1994593113 title "A General Strategy for the Rational Design of Size-Selective Mesoporous Catalysts" @default.
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- W1994593113 doi "https://doi.org/10.1002/chem.200601598" @default.
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