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- W1994624279 abstract "The new phosphovanadate Co(NH3)6(V1.5P0.5)O6OH has been synthesized by a hydrothermal method at 220°C. It crystallizes in the P21/c space group with a=9.5206(8), b=6.9631(6), c=17.108(1), β=93.028(7), and Z=4. The structural resolution using single-crystal X-ray diffraction leads to R(Fo)=3.63% and Rw(F2o)=10.67%. This structure consists of [Co(NH3)6]3+ cations and [V1.5P0.5O6OH]3− anions assembled in a distorted rock salt arrangement. The presence of the Co(III) hexammine complex [Co(NH3)6]3+ is particularly original in this structure since no complexes have been isolated up to now in phosphovanadates. The V1.5P0.5O6OH diphosphovanadate group, with one vanadium tetrahedral site and one tetrahedral site statistically occupied by 0.5 vanadium and 0.5 phosphorus atom, corresponds to the random distribution of V2O6OH and VPO6OH groups as confirmed by the IR spectroscopy study. Magnetic measurements show that the Co(III) cation adopts a low spin configuration." @default.
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- W1994624279 date "2001-06-01" @default.
- W1994624279 modified "2023-09-26" @default.
- W1994624279 title "A Novel Phosphovanadate of Co(III) Hexammine: Co(NH3)6(V1.5P0.5)O6OH" @default.
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- W1994624279 doi "https://doi.org/10.1006/jssc.2001.9185" @default.
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