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- W1994643693 abstract "The proton and fluorine magnetic resonance spectra with natural abundance carbon-13 satellites of meta-difluorobenzene dissolved in nematic liquid crystals were analyzed. The complete rα structure was determined. The structure deviates clearly from hexagonal. Evidence has been found of an anisotropy in the indirect fluorine-fluorine and fluorine-carbon-13 couplings. From the analyses of the 19F and 19F13C satellite spectra the 13C(12C) isotope effects on the 19F chemical shift were calculated. The orientational behavior of meta-difluorobenzene was compared with that predicted by theoretical models based on dispersion and repulsion interactions. The data obtained from ZLI 1167 and ZLI 1132 liquid crystals are in agreement with the theory based on dispersion forces, but in other solvents specific interactions also seem to be of importance." @default.
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- W1994643693 date "1983-10-01" @default.
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- W1994643693 title "1H and 19F NMR study of meta-difluorobenzene: Structure, J-coupling anisotropy, and orientational behavior" @default.
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- W1994643693 doi "https://doi.org/10.1016/0022-2364(83)90323-2" @default.
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