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• W1994657354 startingPage "8295" @default.
• W1994657354 abstract "The new binary antimonide Ti2Sb was found to crystallize in a distorted variant of the La2Sb type, which contains a square planar La net with short La−La bonds. In the Ti2Sb structure, the corresponding Ti net is deformed to squares and rhombs in order to enhance Ti−Ti bonding, as proven by single-crystal X-ray investigation in combination with the real-space pair distribution function technique utilizing both X-ray and neutron powder diffraction data. Electronic structure calculations revealed a lowering of the total energy caused by the disorder, the major driving force being strengthened Ti−Ti interactions along the diagonal of the Ti4 rhombs." @default.
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• W1994657354 date "2004-06-15" @default.
• W1994657354 modified "2023-10-16" @default.
• W1994657354 title "Planar Nets of Ti Atoms Comprising Squares and Rhombs in the New Binary Antimonide Ti₂Sb" @default.
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• W1994657354 doi "https://doi.org/10.1021/ja048262e" @default.
• W1994657354 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/15225072" @default.
• W1994657354 hasPublicationYear "2004" @default.
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