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- W1994692815 abstract "A new method of estimating the effective charges on palladium and platinum in the square planar complexes PdCl42−, PtCl42−, PdBr42− and PtBr42− is described in detail. It turns out that Cl is more electronegative than Br and Pt is more electronegative than Pd in these complexes. It is shown further that the strikingly long PtPt distance between the complexes in K2PtCl4 is caused by the K+ ions, probably together with dispersion forces, but is not the result of electrostatic repulsion between the PtCl42− units. The analysis accounts for the “blue shift” of the 1A1g−3Eg transition in the absorption spectrum of the PtCl42− complex observed in high pressure spectroscopic experiments by Interrante et al." @default.
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- W1994692815 title "Electrostatic energy calculations for potassium chloroplatinite and related compounds" @default.
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- W1994692815 doi "https://doi.org/10.1016/0022-1902(76)80136-4" @default.
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