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• W1994703542 startingPage "4152" @default.
• W1994703542 abstract "The micelles of two tripropargylammonium-functionalized cationic surfactants were cross-linked by a disulfide-containing diazido cross-linker in the presence of Cu(I) catalysts. With multiple residual alkyne groups on the surface, the resulting surface cross-linked micelles (SCMs) were postfunctionalized by reaction with 2-azidoethanol and an azido-terminated poly(ethylene glycol), respectively, via the alkyne–azide click reaction. The water-soluble nanoparticles obtained had low surface activity due to the buried hydrophobic tails. Cleavage of the disulfide cross-links by dithiothreitol (DTT) exposed the hydrophobic tails and resumed surface activity of the “caged” surfactants within 2 min after DTT addition. The controlled breakage of the SCMs was used to lower the surface tension of aqueous solutions and trigger the release of liposomal contents on demand." @default.
• W1994703542 created "2016-06-24" @default.
• W1994703542 creator A5023367767 @default.
• W1994703542 creator A5048294684 @default.
• W1994703542 date "2012-02-22" @default.
• W1994703542 modified "2023-09-28" @default.
• W1994703542 title "Protection/Deprotection of Surface Activity and Its Applications in the Controlled Release of Liposomal Contents" @default.
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• W1994703542 doi "https://doi.org/10.1021/la2050702" @default.
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