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- W1994707945 abstract "Several types of active carbons were used to support Mo(CO)6 and the resultant Mo(CO)6/carbon was used for the homologation of ethene to yield propene as well as the metathesis of propene. Effects of pretreatment of carbon and evacuation temperature of Mo (CO)6/carbon on the catalytic activities were examined. Treatment of carbon with acids, such as hydrochloric and nitric, as well as air oxidation resulted in a pronounced enhancement in the catalytic activity regardless of the carbon sources. Supported Mo (CO)6 decomposed thermally in such a way that all carbonyl ligands were lost in rapid succession without yielding intermediate subcarbonyl species. The effect of the oxidation was interpreted in terms of the contribution of surface oxygenated compounds to control the oxidation states of decomposed Mo(CO)6." @default.
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- W1994707945 date "1992-08-01" @default.
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- W1994707945 title "Catalytic properties of Mo (CO)6 supported on activated carbon for ethene homologation" @default.
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- W1994707945 doi "https://doi.org/10.1016/0926-860x(92)80173-a" @default.
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