Matches in SemOpenAlex for { <https://semopenalex.org/work/W1994739925> ?p ?o ?g. }
- W1994739925 endingPage "1061" @default.
- W1994739925 startingPage "1054" @default.
- W1994739925 abstract "We prepared tubular crystals of the hydrated hydroxyl-acid, (1R*,5R*)-7,7-diallyl-5-hydroxymethyl-6-oxabicyclo[3.2.1]octane-1-carboxylic acid, (±)9·2H2O. Crystals grew in a solution of water and carbon tetrachloride under a water vapor atmosphere. These hollow macrocrystals had mostly hexagonal cross sections and were, on average, approximately 5−10 mm in length, with internal diameters in the range of 300−500 μm, and wall thicknesses in the range of 250−400 μm. The experimental results showed that crystal growth was compatible with a lattice defect mechanism, where vacancies corresponded to sub-nano-liquid glassy regions, where water “diffusion” and monomer “dissolution” processes occurred. We propose that the mechanism underlying the formation of the tubular structures is a “build-and-etch” growth process. The etching, or dissolution, started at the middle of each of the basal surfaces of a solid prism and continued along the inside of the long axis; thus, the solid crystals gradually converted into semitubes, which finally became complete hollow tubes. Recrystallization on the external surface was concomitant with the dissolution process; this increased the diameters of the final tubes compared to those of the initial solid prisms." @default.
- W1994739925 created "2016-06-24" @default.
- W1994739925 creator A5022305100 @default.
- W1994739925 creator A5023100785 @default.
- W1994739925 creator A5036898507 @default.
- W1994739925 creator A5039333773 @default.
- W1994739925 date "2011-02-25" @default.
- W1994739925 modified "2023-09-24" @default.
- W1994739925 title "Water-Induced Molecular Self-Assembly of Hollow Tubular Crystals" @default.
- W1994739925 cites W1979182415 @default.
- W1994739925 cites W1983069685 @default.
- W1994739925 cites W1983137443 @default.
- W1994739925 cites W1983939870 @default.
- W1994739925 cites W1989073536 @default.
- W1994739925 cites W1998920258 @default.
- W1994739925 cites W2001804099 @default.
- W1994739925 cites W2003829553 @default.
- W1994739925 cites W2003857515 @default.
- W1994739925 cites W2011535974 @default.
- W1994739925 cites W2016005311 @default.
- W1994739925 cites W2018629314 @default.
- W1994739925 cites W2019387305 @default.
- W1994739925 cites W2021826401 @default.
- W1994739925 cites W2027848974 @default.
- W1994739925 cites W2030835964 @default.
- W1994739925 cites W2035438422 @default.
- W1994739925 cites W2037288322 @default.
- W1994739925 cites W2050504983 @default.
- W1994739925 cites W2056853419 @default.
- W1994739925 cites W2059240808 @default.
- W1994739925 cites W2063556626 @default.
- W1994739925 cites W2068223941 @default.
- W1994739925 cites W2073833402 @default.
- W1994739925 cites W2074649595 @default.
- W1994739925 cites W2075528212 @default.
- W1994739925 cites W2075824988 @default.
- W1994739925 cites W2078237016 @default.
- W1994739925 cites W2078574309 @default.
- W1994739925 cites W2079245612 @default.
- W1994739925 cites W2091029987 @default.
- W1994739925 cites W2092937436 @default.
- W1994739925 cites W2093794538 @default.
- W1994739925 cites W2114269846 @default.
- W1994739925 cites W2116716969 @default.
- W1994739925 cites W2123939692 @default.
- W1994739925 cites W2140773507 @default.
- W1994739925 cites W2145168235 @default.
- W1994739925 cites W2152417280 @default.
- W1994739925 cites W2155337439 @default.
- W1994739925 cites W2155405795 @default.
- W1994739925 cites W2326346263 @default.
- W1994739925 cites W2949885582 @default.
- W1994739925 cites W2952214321 @default.
- W1994739925 cites W2952730952 @default.
- W1994739925 cites W3101392086 @default.
- W1994739925 cites W62192764 @default.
- W1994739925 doi "https://doi.org/10.1021/cg101227u" @default.
- W1994739925 hasPublicationYear "2011" @default.
- W1994739925 type Work @default.
- W1994739925 sameAs 1994739925 @default.
- W1994739925 citedByCount "20" @default.
- W1994739925 countsByYear W19947399252012 @default.
- W1994739925 countsByYear W19947399252013 @default.
- W1994739925 countsByYear W19947399252014 @default.
- W1994739925 countsByYear W19947399252015 @default.
- W1994739925 countsByYear W19947399252016 @default.
- W1994739925 countsByYear W19947399252017 @default.
- W1994739925 countsByYear W19947399252018 @default.
- W1994739925 countsByYear W19947399252019 @default.
- W1994739925 countsByYear W19947399252020 @default.
- W1994739925 countsByYear W19947399252021 @default.
- W1994739925 countsByYear W19947399252023 @default.
- W1994739925 crossrefType "journal-article" @default.
- W1994739925 hasAuthorship W1994739925A5022305100 @default.
- W1994739925 hasAuthorship W1994739925A5023100785 @default.
- W1994739925 hasAuthorship W1994739925A5036898507 @default.
- W1994739925 hasAuthorship W1994739925A5039333773 @default.
- W1994739925 hasConcept C127413603 @default.
- W1994739925 hasConcept C151730666 @default.
- W1994739925 hasConcept C178790620 @default.
- W1994739925 hasConcept C185592680 @default.
- W1994739925 hasConcept C192562407 @default.
- W1994739925 hasConcept C195702682 @default.
- W1994739925 hasConcept C199360897 @default.
- W1994739925 hasConcept C200447597 @default.
- W1994739925 hasConcept C2781285689 @default.
- W1994739925 hasConcept C41008148 @default.
- W1994739925 hasConcept C42360764 @default.
- W1994739925 hasConcept C8010536 @default.
- W1994739925 hasConcept C86803240 @default.
- W1994739925 hasConcept C88380143 @default.
- W1994739925 hasConceptScore W1994739925C127413603 @default.
- W1994739925 hasConceptScore W1994739925C151730666 @default.
- W1994739925 hasConceptScore W1994739925C178790620 @default.
- W1994739925 hasConceptScore W1994739925C185592680 @default.
- W1994739925 hasConceptScore W1994739925C192562407 @default.
- W1994739925 hasConceptScore W1994739925C195702682 @default.
- W1994739925 hasConceptScore W1994739925C199360897 @default.