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• W1994741707 abstract "We report on the synthesis and characterization of two amphiphilic biomimetic assemblies grown on electrochemically oxidized gold- and indium-doped tin oxide substrates. The molecular assemblies are bound covalently to the substrates by the reaction of the surface oxide with acid chlorides to form ester-like bonds, creating a hydrophilic region adjacent to the substrate. One assembly possesses a moiety capable of forming a second hydrophilic region with amides that can participate in a hydrogen-bonding network within the monolayer (C6−A−C12), and the other is an aliphatic structure (tetradecane, C14). These interfacial structures, presenting hydrophobic aliphatic chains to an adsorbate, constitute a useful system for the subsequent deposition of a lipid monolayer, leading to the formation of a hybrid bilayer membrane. Examination of the capacitance, cyclic voltammetry, and FTIR data for the C6−A−C12 and C14 systems demonstrates their stability and organization, while preserving some fluidlike behavior characteristic of the hydrophilic regions, essential for biomimetic applications." @default.
• W1994741707 created "2016-06-24" @default.
• W1994741707 creator A5002615133 @default.
• W1994741707 creator A5088186601 @default.
• W1994741707 date "2003-03-27" @default.
• W1994741707 modified "2023-10-16" @default.
• W1994741707 title "Synthesis and Characterization of Amphiphilic Biomimetic Assemblies at Electrochemically Active Surfaces" @default.
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• W1994741707 doi "https://doi.org/10.1021/la026946z" @default.
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