FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W1994745651> ?p ?o ?g. }

• W1994745651 endingPage "3189" @default.
• W1994745651 startingPage "3182" @default.
• W1994745651 abstract "Naturally occurring β-methylstyrenes, such as anethole (Ane), isosafrole (ISa), methyl isoeugenol (MIEu), and acetyl isoeugenol (AcIEu), which are phenylpropanoids and possess electron-donating alkoxy substituents on an aromatic ring, were copolymerized with common acrylic monomers, such as methyl (MA), n-butyl (nBA), and tert-butyl acrylates (tBA), N,N-dimethylacrylamide and diethyl fumarate in toluene and fluoroalcohols. The copolymerizations of β-methylstyrenes (M1) and acrylic monomers (M2) were fitted well by the chain-end model. The relative reactivity of β-methylstyrenes with the acrylic radicals (1/r2) was enhanced up to 3 times in m-C6H4[C(CF3)2OH]2 compared to toluene, whereas no homo-propagation of β-methylstyrenes occurred in any solvent (r1 ∼ 0) because of the sterically hindered 1,2-disubstituted vinyl structure of β-methylstyrenes. The copolymerizability was also dependent on the substituents of both monomers: the relative reactivity of the β-methylstyrenes generally increased with the decreasing bulkiness of both β-methylstyrenes [1/r2 = 1/1.07 (AcIEu/MA), 1/0.62 (MIEu/MA), 1/0.53 (ISa/MA), 1/0.46 (Ane/MA)] (bulkiness: AcIEu > MIEu > Isa > Ane) and acrylates [1/r2 = 1/0.87 (Ane/tBA), 1/0.67 (Ane/nBA), 1/0.46 (Ane/MA)] (bulkiness: tBA > nBA > MA). The reversible addition–fragmentation chain-transfer copolymerization of Ane or ISa with MA proceeded in both toluene and m-C6H4[C(CF3)2OH]2, allowing molecular weight control of the copolymers. The incorporation of β-methylstyrene units into the copolymers was thus increased up to ∼45 mol% (∼60 wt%) by fluoroalcohol, resulting in high-performance polymers with relatively high glass transition temperatures (Tg > 100 °C), even when using common alkyl acrylates as the comonomers." @default.
• W1994745651 created "2016-06-24" @default.
• W1994745651 creator A5003740584 @default.
• W1994745651 creator A5011393219 @default.
• W1994745651 creator A5018686938 @default.
• W1994745651 date "2014-01-01" @default.
• W1994745651 modified "2023-09-23" @default.
• W1994745651 title "Renewable β-methylstyrenes for bio-based heat-resistant styrenic copolymers: radical copolymerization enhanced by fluoroalcohol and controlled/living copolymerization by RAFT" @default.
• W1994745651 cites W1495482938 @default.
• W1994745651 cites W1973601387 @default.
• W1994745651 cites W1987009571 @default.
• W1994745651 cites W1993477778 @default.
• W1994745651 cites W2007231064 @default.
• W1994745651 cites W2014755996 @default.
• W1994745651 cites W2018103807 @default.
• W1994745651 cites W2021178176 @default.
• W1994745651 cites W2021755267 @default.
• W1994745651 cites W2037132535 @default.
• W1994745651 cites W2040062967 @default.
• W1994745651 cites W2044618796 @default.
• W1994745651 cites W2047739959 @default.
• W1994745651 cites W2058025805 @default.
• W1994745651 cites W2059243787 @default.
• W1994745651 cites W2067468996 @default.
• W1994745651 cites W2084555720 @default.
• W1994745651 cites W2084665655 @default.
• W1994745651 cites W2105075918 @default.
• W1994745651 cites W2118665381 @default.
• W1994745651 cites W2123333244 @default.
• W1994745651 cites W2124025731 @default.
• W1994745651 cites W2150640616 @default.
• W1994745651 cites W2159719930 @default.
• W1994745651 cites W2170981512 @default.
• W1994745651 cites W2321571472 @default.
• W1994745651 cites W2553340846 @default.
• W1994745651 doi "https://doi.org/10.1039/c3py01066j" @default.
• W1994745651 hasPublicationYear "2014" @default.
• W1994745651 type Work @default.
• W1994745651 sameAs 1994745651 @default.
• W1994745651 citedByCount "38" @default.
• W1994745651 countsByYear W19947456512013 @default.
• W1994745651 countsByYear W19947456512014 @default.
• W1994745651 countsByYear W19947456512015 @default.
• W1994745651 countsByYear W19947456512016 @default.
• W1994745651 countsByYear W19947456512017 @default.
• W1994745651 countsByYear W19947456512018 @default.
• W1994745651 countsByYear W19947456512019 @default.
• W1994745651 countsByYear W19947456512020 @default.
• W1994745651 countsByYear W19947456512021 @default.
• W1994745651 countsByYear W19947456512022 @default.
• W1994745651 countsByYear W19947456512023 @default.
• W1994745651 crossrefType "journal-article" @default.
• W1994745651 hasAuthorship W1994745651A5003740584 @default.
• W1994745651 hasAuthorship W1994745651A5011393219 @default.
• W1994745651 hasAuthorship W1994745651A5018686938 @default.
• W1994745651 hasConcept C111998727 @default.
• W1994745651 hasConcept C121120078 @default.
• W1994745651 hasConcept C142724271 @default.
• W1994745651 hasConcept C15920480 @default.
• W1994745651 hasConcept C166940927 @default.
• W1994745651 hasConcept C178790620 @default.
• W1994745651 hasConcept C185592680 @default.
• W1994745651 hasConcept C188027245 @default.
• W1994745651 hasConcept C204787440 @default.
• W1994745651 hasConcept C2776910235 @default.
• W1994745651 hasConcept C2778142098 @default.
• W1994745651 hasConcept C2780263894 @default.
• W1994745651 hasConcept C521977710 @default.
• W1994745651 hasConcept C71924100 @default.
• W1994745651 hasConcept C90150868 @default.
• W1994745651 hasConcept C9132879 @default.
• W1994745651 hasConceptScore W1994745651C111998727 @default.
• W1994745651 hasConceptScore W1994745651C121120078 @default.
• W1994745651 hasConceptScore W1994745651C142724271 @default.
• W1994745651 hasConceptScore W1994745651C15920480 @default.
• W1994745651 hasConceptScore W1994745651C166940927 @default.
• W1994745651 hasConceptScore W1994745651C178790620 @default.
• W1994745651 hasConceptScore W1994745651C185592680 @default.
• W1994745651 hasConceptScore W1994745651C188027245 @default.
• W1994745651 hasConceptScore W1994745651C204787440 @default.
• W1994745651 hasConceptScore W1994745651C2776910235 @default.
• W1994745651 hasConceptScore W1994745651C2778142098 @default.
• W1994745651 hasConceptScore W1994745651C2780263894 @default.
• W1994745651 hasConceptScore W1994745651C521977710 @default.
• W1994745651 hasConceptScore W1994745651C71924100 @default.
• W1994745651 hasConceptScore W1994745651C90150868 @default.
• W1994745651 hasConceptScore W1994745651C9132879 @default.
• W1994745651 hasIssue "9" @default.
• W1994745651 hasLocation W19947456511 @default.
• W1994745651 hasOpenAccess W1994745651 @default.
• W1994745651 hasPrimaryLocation W19947456511 @default.
• W1994745651 hasRelatedWork W1514942051 @default.
• W1994745651 hasRelatedWork W1574720955 @default.
• W1994745651 hasRelatedWork W1996505194 @default.
• W1994745651 hasRelatedWork W2025232569 @default.
• W1994745651 hasRelatedWork W2047588656 @default.
• W1994745651 hasRelatedWork W2104952315 @default.
• W1994745651 hasRelatedWork W2129821659 @default.

• next