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- W1994747694 abstract "It is well known that in equilibrated solid alloys surface and bulk compositions can differ appreciably. For homogeneous alloys two theories of surface enrichment are available, which in the present work are checked against new experimental data. One of these theories is based on the regular solution model of liquids and neglects lattice strain effects. It predicts surface enrichment with the component having the lowest heat of atomization. The second theory, which concentrates on differences in atomic radii and is often used to compute grain boundary segregation, predicts enrichment with the atom having the largest radius. Auger electron spectroscopy results are reported for the alloys Au3Cu and Au Cu3, for which the two theories predict opposite surface enrichments. It is concluded that the effects due to strain and heats of atomization, which would cause surface enrichments of opposite sign, just cancel out." @default.
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- W1994747694 date "1975-01-01" @default.
- W1994747694 modified "2023-10-16" @default.
- W1994747694 title "Surface enrichment in Cu3Au and Au3Cu alloys" @default.
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- W1994747694 doi "https://doi.org/10.1016/0039-6028(75)90272-1" @default.
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