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• W1994750353 abstract "Electrosubstitution of alkali cations in mixed-alkali glass containing both Na2O and K2O for other monovalent metal cations (M+=Li+, Ag+, and Cs+) was investigated using a solid-state electrochemical method. The fundamental electrolysis system consists of anode/M+-conducting microelectrode/glass/Na-β″-Al2O3/cathode, where M+ is substituted for the alkali metal ions in the glass under an applied electric field. Li+ ions attacked only Na+ sites, and Ag+ ions replaced Na+ sites more readily than K+. In contrast, Cs+ ions simultaneously substituted for both Na+ and K+ sites. The substitution behavior appears to depend on the difference in ionic conductivity between K+ and Na+ and the radius of the dopant. This mechanism was discussed qualitatively." @default.
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• W1994750353 date "2004-01-01" @default.
• W1994750353 modified "2023-09-23" @default.
• W1994750353 title "Selective substitution of alkali cations in mixed alkali glass by solid-state electrochemistry" @default.
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• W1994750353 doi "https://doi.org/10.1016/s0022-4596(03)00399-2" @default.
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