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- W1994752495 abstract "Ru(ONO)2 and Os(ONO)2 distort from octahedral towards trigonal prismatic geometry in order to relieve π antibonding due to donation from the second-highest ligand orbital to the metal. Increasing oxidation of the ONO ligand suppresses distortion by increasing σ* interactions in the trigonal prism." @default.
- W1994752495 created "2016-06-24" @default.
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- W1994752495 date "2014-01-01" @default.
- W1994752495 modified "2023-10-16" @default.
- W1994752495 title "Octahedral to trigonal prismatic distortion driven by subjacent orbital π antibonding interactions and modulated by ligand redox noninnocence" @default.
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- W1994752495 doi "https://doi.org/10.1039/c4cc03404j" @default.
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