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- W1994774788 abstract "The empty space in different crystalline and clathrate phases of syndiotactic polystyrene (s-PS) is evaluated by a numerical procedure. It is shown that the δ form is nanoporous and includes two identical cavities per unit cell, whose shape and volume are characterized. As a consequence of clathration, the unit cell of the δ form is enlarged and the cavity is able to include molecules definitely larger than its starting size. Sorption experiments of nitrogen at 77 K for s-PS powders in different crystalline forms are also presented. These can be interpreted by inclusion of three nitrogen molecules per cavity of the δ crystalline phase and hence give an independent estimate of its volume." @default.
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- W1994774788 date "2001-04-03" @default.
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- W1994774788 title "Shape and Volume of Cavities in Thermoplastic Molecular Sieves Based on Syndiotactic Polystyrene" @default.
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- W1994774788 doi "https://doi.org/10.1021/cm001089a" @default.
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