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- W1994781331 abstract "The deoxyoligonucleotide, d(CCCGCGGG), forms a duplex structure that can be put into the A and B forms in films by changing the ambient humidity and into the Z form by adding a heavy metal ion such as Ni(II). Since this oligomer contains only the bases, C and G, these spectra permit us to easily identify the infrared marker bands of C and G that correspond to the three different conformations. In addition, marker bands belonging mainly to the sugar and phosphate groups of the backbone are also reported. Equilibration with D2O at various humidities allows us to obtain the i.r. bands of the hydrogen—deuterium exchanged films. Two tables are presented in which the i.r. bands are listed and assigned. One table lists the bands of this oligomer in the B, A and Z forms in H2O while the second lists the i.r. bands after deuterium exchange. In this way a catalog of i.r. bands is made available for the identification of the local conformation of the C and G bases in DNA that may be heterogeneous in conformation." @default.
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- W1994781331 date "1990-01-01" @default.
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- W1994781331 title "Polymorphism of the d(CCCGCGGG)2 double helix studied by FT-i.r. spectroscopy" @default.
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- W1994781331 doi "https://doi.org/10.1016/0584-8539(93)80018-6" @default.
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