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- W1994784911 abstract "A total synthesis of title cis-clerodane diterpene 9 has been achieved starting from a bicyclic intermediate 4, which was developed previously by us. Firstly the compound 4 was converted by five steps to octalone derivative 6, of which angular methylation, with the protection of 3-methylene group, afforded cis-decalone 7. Appendage of 3-furyl group and deoxygenation at C-20 carbon atom transformed the compound 7 to furanoid ketone 8. Methylenation of 8 followed by the double bond isomerization led to the completion of the synthesis." @default.
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- W1994784911 date "1990-06-01" @default.
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- W1994784911 title "Synthetic Studies on Terpenoid Compounds. XXXIII. A Total Synthesis of (±)-15,16-Epoxy-<i>cis</i>-cleroda-3,13(16),14-triene" @default.
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- W1994784911 doi "https://doi.org/10.1246/bcsj.63.1720" @default.
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