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• W1994835897 abstract "Abstract The reactivity of the trinuclear imido‐nitrido complex [{Ti(η 5 ‐C 5 Me 5 )(μ‐NH)} 3 (μ 3 ‐N)] ( 1 ) and derivatives thereof withiodine has been investigated. Treatment of the indium( I )adduct [IIn{(μ 3 ‐NH) 3 Ti 3 (η 5 ‐C 5 Me 5 ) 3 (μ 3 ‐N)}] ( 2 ) with I 2 (1 equiv.) in benzene afforded the indium( III ) complex [I 3 In{(μ 3 ‐NH) 3 Ti 3 (η 5 ‐C 5 Me 5 ) 3 (μ 3 ‐N)}] ( 3 ), but with excess of iodine the precipitation of orange crystals of the ionic complex [Ti 3 (η 5 ‐C 5 Me 5 ) 3 I 2 (μ‐NH) 3 (NH 3 )][InI 4 ] ( 4 ) takes place. Analogous treatment of the metalloligand 1 with I 2 in toluene gave initially the iodine( I ) derivative [I{(μ 3 ‐NH) 3 Ti 3 (η 5 ‐C 5 Me 5 ) 3 (μ 3 ‐N)}][I 3 ] ( 5 ). Surprisingly, toluene solutions of 5 at room temperature produced crystals of the ionic complex [Ti 3 (η 5 ‐C 5 Me 5 ) 3 I 2 (μ‐NH) 3 (NH 3 )][I 3 ] · C 7 H 8 ( 6· C 7 H 8 ). The trinuclear titanium cation [Ti 3 (η 5 ‐C 5 Me 5 ) 3 I 2 (μ‐NH) 3 (NH 3 )] + of complexes 4 and 6 has been structurally characterized by a combination of X‐ray and DFT studies. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2006)" @default.
• W1994835897 created "2016-06-24" @default.
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• W1994835897 date "2006-03-01" @default.
• W1994835897 modified "2023-09-23" @default.
• W1994835897 title "Iodine Attack on the Metalloligand [{Ti(η⁵‐C₅Me₅)(μ‐NH)}₃(μ₃‐N)]: Surprising Formation of the [Ti₃(η⁵‐C₅Me₅)₃I₂(μ‐NH)₃(NH₃)]⁺ Cation" @default.
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• W1994835897 doi "https://doi.org/10.1002/ejic.200500840" @default.
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