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- W1994836812 abstract "Linear and Star-shaped PCL-b-PEG copolymers were synthesized through a two step process, including the first step to synthesize the star-shaped PCL through ring-opening polymerization of Γ-caprolactone initiated from multi-functional alcohol under the existence of tin(II) ethylhexanoate [Sn(Oct)2] catalyst, and the following step to couple the obtained star-shaped PCL with PEG segments using bi-functional linker. The structure of the polymers was confirmed by IR, NMR, GPC, et al. The aggregation behaviors of the star-shape copolymers were compared with that of the linear block copolymer with corresponding molecular weight of each arm, and the influences of structure factors were discussed." @default.
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- W1994836812 date "2007-07-01" @default.
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- W1994836812 title "Star-Shaped Poly (Γ-Caprolactone-b-Ethylene Glycol): Synthesis, Characterization and Aggregation Behavior" @default.
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- W1994836812 doi "https://doi.org/10.4028/www.scientific.net/kem.342-343.725" @default.
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