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• W1994855295 startingPage "184" @default.
• W1994855295 abstract "Abstract A series of new mer -[Ru(dpop′)(N–N)Cl](PF 6 ) (N–N = 2,2-bipyrimidine (bpy); 1,10-phenanthroline (phen); 2,2′-bipyrimidine (bpm) and ethylenediamine (en)) complexes was prepared and the effect of N–N on physical properties of the complexes compared. The Ru dπ → dpop′ π ∗ MLCT transition dominates the lower energy visible spectrum and increases in energy as N–N varies en  ∗ and intraligand π → π ∗ transitions are observed at higher energy. Cyclic voltammetry results show increasingly stabilized Ru(II) dπ orbitals in the order of N–N variation en  ∗ backbonding ligand. Spectro-electrochemical data show reversible one electron oxidative and reductive processes for all mer -[Ru(dpop′)(N–N)Cl] + complexes except N–N = en. 1 H; 13 C and 2-D NMR data in CH 3 CN presented support the proposed structures. 1 H NMR data was also used to verify the Cl − substitution in D 2 O. Aquation yields the mer -[Ru(dpop′)(N–N)(H 2 O)] +2 complexes with pseudo first order kinetics and the lability of Cl − follows a trend with the N–N group bpm" @default.
• W1994855295 created "2016-06-24" @default.
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• W1994855295 date "2015-05-01" @default.
• W1994855295 modified "2023-09-25" @default.
• W1994855295 title "Synthesis and characterization of a series of ruthenium(II) complexes with a tetraazapolyaromatic tridentate ligand dipyrido (2,3- a :3′,2′- j )phenazine" @default.
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• W1994855295 doi "https://doi.org/10.1016/j.ica.2015.03.001" @default.
• W1994855295 hasPublicationYear "2015" @default.
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